CO2 and Steam Co-Electrolysis for Resource Utilization in Space

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CO2 and Steam Co-Electrolysis for Resource Utilization in Space ( co2-and-steam-co-electrolysis-resource-utilization-space )

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The HYSYS calculates the power necessary to split the water. A component splitter follows to separate the oxygen from the hydrogen. The electrolysis process conditions are set to near ambient conditions. Figure 8 represents a slightly modified Bosch process flow model. The Bosch reactor in this case operates at sub-atmospheric conditions and the electrolysis process operates at atmospheric conditions. Pumps are used instead of compressors for this model. The final modification to the basic Bosch process model is the replacement of the three compressors with one compressor, as shown in Figure 9. This model represents a Bosch system with minimum number of process equipment, in terms of the number of compressor. B. Sabatier Process Model The Sabatier process is shown in Figure 10. In this model, the Sabatier reactor receives a combined stream of CO2 and hydrogen from LPCOR and the electrolysis unit, respectively at 79kPa (11.5psia). The process flow diagram of the model is shown in Figure 10. Figure 10. Process flow diagram of base Sabatier process The overall Sabatier reaction is simulated by using two equilibrium reactors, a lower temperature reactor at 240°C and a higher temperature reactor at 565°C. Heat recuperation occurs at the inlet and outlet of the total reactor and in between the two equilibrium reactors. The equilibrium reactors calculate the outlet compositions based on a default tabulated methanation data within the HYSYS.Plant software. The outlet stream from the Sabatier reactor is cooled and is water condensed within the water knockout tank (condenser). The condensate is added to main water stream before entering the water electrolyzer. The gas stream exiting the water knockout tank is compressed to atmospheric conditions and released. This gas stream primarily contains methane and some carbon dioxide and water and trace amounts of hydrogen. The Sabatier and Bosch models use the same electrolysis process model. The hydrogen to carbon dioxide ratio for this model was maintained at 3.5 by adjusting the water inlet flow. 9 American Institute of Aeronautics and Astronautics

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