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Figure 16. Process flow diagram of hydrogenation process with co-electrolysis 6. Hydrogenation and co-electrolysis integrated model Hydrogenation is a process by which carbon monoxide and hydrogen are in equilibrium with water and carbon. Equilibrium data for the hydrogenation process were integrated into a HYSYS equilibrium reactor to simulate the process. CO + H2H2O + C (18) The hydrogenation process was combined with high-temperature co-electrolysis to develop an alternative oxygen producing process as shown in Figure 16. Compressed carbon dioxide is heated using the hot oxygen stream exiting the co-electrolysis unit. The exit gas stream from the hydrogenation reactor, which is about 50% hydrogen and 40% steam by mole is mixed with the carbon dioxide and heated to over 700°C by the syngas and water mixture exiting the electrolysis unit. The gas is then heated to the electrolysis process temperature by an electric heater. Oxygen and a syngas stream are produced from the electrolysis unit. The syngas reacts in the hydrogenation reactor at a pressure of 172 kPa (25psia) and a temperature of 350°C to produce carbon and water. Ideally, the hydrogen and water within this overall process is recycled and therefore no need to replenish either. 18 American Institute of Aeronautics and AstronauticsPDF Image | CO2 and Steam Co-Electrolysis for Resource Utilization in Space
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