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CO2 removal from air for alkaline fuel cells operating with liquid H2

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CO2 removal from air for alkaline fuel cells operating with liquid H2 ( co2-removal-from-air-alkaline-fuel-cells-operating-with-liqu )

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Chapter 6 Conclusions and recommendations It has been said that in a hydrogen economy, a time when hydrogen becomes widely available and used as a major transportation fuel, the use of alkaline fuel cells for transport power generation will be favoured over other types of fuel cells. This is because alkaline fuel cells are inherently more efficient and the range of materials which may be used as electrocatalysts or for structural elements is much larger for alkaline media than for acid media. The direct availability of hydrogen, ie. a supply independent of reformed hydrocarbon fuels, would alleviate the problem of CO2 intolerance of alkaline fuel cells associated with the fuel. The CO2 content of air remains a problem. Research and demonstration projects on hydrogen-air alkaline fuel cell powered vehicles have so far used expendable adsorbers for scrubbing CO2 from the air. These adsorbers represent a substantial added weight and occupy a large volume when used for other than low power or short duration applications. Large scale use of non-reusable scrubbers would create the added problem of distribution, and disposal of the spent adsorptive material. The research undertaken in this project established that a regenerable process for CO2 removal from alkaline fuel cell feed air by refrigeration purification, using the cooling available from thermomechanical exergy recovery from liquid hydrogen, IS achievable. 6.1 Conclusions The experimental work conducted showed that CO2 removal from air to below 10ppm is possible using the proposed process. Water condensation and re-vaporisation which must occur as part of this process, has been demonstrated using a reversing heat exchanger. Regeneration for the heat exchanger in which the CO2 was deposited was achieved by allowing it to warm up through a temperature range of 18°C. The increase of the pressure differential between inlet and outlet air streams was linked to outlet CO2 concentration and thus offers a method for controlling regeneration timing. Heat transfer effectiveness was measured at 93%±2.5%. These results collectively indicate that the proposed CO2 removal process functioned as designed, with a 93% internal refrigeration recovery. The testing has demonstrated that even with a hydrogen-air mass ratio as low as that for normal alkaline fuel cell operation, it is possible to effect CO2 removal using exergy recovery if high effectiveness heat exchangers are used. With improved design of the cross-over valves and actuator used with the reversing heat exchanger, it is quite

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