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Chapter 3 Impregnated membranes for DMFCs at high methanol concentrations all cases SPPEK1.6 swells more than SPPEK1.4 due to its higher ion- exchange capacity. The swelling of the impregnated membranes are lower than pure membranes due to the presence of hydrophobic PE substrate. 50 40 30 20 10 50 40 30 20 10 (a) Ultra pure water (b)10M methanol SP P E K 1. 6 SPPEK1.4 SP P E K1 . 6- P E SP P E K1 . 4- P E S P P EK 1 . 6 SPPEK1.4-PE SPPEK1.4 SPPEK1.6-PE 00 0 50 100 150 200 time [h] 0 50 100 150 200 time [h] Figure 3. Swelling degrees by weight in (a) ultra pure water and (b) 10M methanol solution. Figure 4a and 4b show the results of the SD by weight and area, respectively, of all membranes at various methanol concentrations. Swelling by weight of SPPEK1.4 and SPPEK1.6 show a slight increase till 6M and then increase more sharply up to 10M methanol concentration (especially, the SPPEK1.6) (Fig. 4a). Swelling by weight of SPPEK1.6 is higher than SPPEK1.4 due to its higher ion-exchange capacity. For comparison, the swelling by weight of N117 and N-PE membranes are much higher than SPPEK and SPPEK-PE membranes at high concentrations and they are in the range of 70% and 50%, respectively [13]. Swelling by weight of both composite membranes (SPPEK1.4-PE and SPPEK1.6-PE) is independent of methanol concentration and almost factor of two lower than the pure SPPEK1.4 and SPPEK1.6 membranes. This is probably due to the suppression of the swelling degree of the composite membranes by the PE substrate. In Figure 4b, one can see similar trends concerning the swelling by area of the various membranes. At higher methanol concentrations, the SD by area of the SPPEK1.4 and SPPEK1.6 increases, but of the composite membranes 43 SD by weight SD by weightPDF Image | Development of membrane materials for direct methanol fuel cells
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