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Chapter 4 NafionĀ®/H-ZSM-5 composite membranes with superior performance for DMFCs tion. Often aggregation of the particle, or phase separation occurs, causing significant change in the membrane morphology in comparison to pure polymer [23]. Besides, the morphology of the interface between the filler and polymer can be a critical determination of the overall transport properties [24]. Perhaps there is a rigidified polymer layer around the filler causing de- crease in the permeability of the methanol through the composite mem- brane. The low cross-over of the DEZ25-5 membrane may be due to rigidifi- cation of the polymer around the particle in conjunction with particle aggre- gation. 3.5. Proton conductivity 2.5 2.0 1.5 1.0 0.5 0.0 012345 Zeolite content [wt.%] Figure 8. Proton conductivities of DE2020 and DEZ membranes as a function of zeolite content. Figure 8 presents the proton conductivities of DE2020 and DEZ membranes as a function of zeolite content. Proton conductivities of all composite membranes are higher than the pure DE2020 membrane, consistent with earlier study [18]. DEZ50-1 shows the highest proton conductivity among the DEZ50 membranes while the conductivities of DEZ25 and DEZ100 do not change significantly with the zeolite content. On the other hand, the conductivity of DEZ75 somewhat scatters with zeolite content in the membrane. 65 DZ50 DZ100 DZ25 DZ75 DE2020 Proton conductivity (*10-2) [S/cm]PDF Image | Development of membrane materials for direct methanol fuel cells
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