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methanol oxidation by oxygen at cathode is a surface reaction and, thus, does not depend on cathode potential. Actually, crossover is promoted with a 112 membrane and the flux probably underestimated by the model in the concerned range of cell voltage. The simulation was done for 117 Nafion membrane, PC = 1atm (rel.), CMeOH = 1M: Figure 56: Theoretical polarization curve for a 117 Nafion membrane at 80oC with Fanode = 5ccm, CCH3OH = 1M and PC = 1atm (rel.) The model, thus, predicts well the performance when cathode pressure is changed (Figure 56). The effect of higher methanol concentration was investigated for 117 Nafion membrane, PC = 0atm (rel.), CMeOH = 5M: - 81 -PDF Image | Direct Methanol Fuel Cell (DMFC) Performance
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