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The model does not accurately account for the cathode overpotential which it underestimates substantially. Further, the model does not take into consideration the inhibition of cathode kinetics as a result of methanol crossover. Finally, the diffusion limitations of methanol through gas-diffusion layer, especially at higher current densities and CO2 evolution, are not included in the model and account for variation at low voltage. Sundmacher et al [11] accounted for the diffusion through the diffusion layer by considering a mass balance for Methanol and carbon dioxide both for the anode compartment and the catalytic layer. A code similar to the code studied previously was written including these two mass balances. It resulted in a modification in the fitted parameters but the shape of the coverage, potentials, and current evolution with time remained the same. This code still not account for methanol diffusion limitation due to carbon dioxide removal. - 83 -PDF Image | Direct Methanol Fuel Cell (DMFC) Performance
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