Direct Methanol Fuel Cell (DMFC) Performance

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Direct Methanol Fuel Cell (DMFC) Performance ( direct-methanol-fuel-cell-dmfc-performance )

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s22 s21 s17 s16 s20 s15 s18 s16 s25 s17 s25 s20 s14 s24 s14 s24 s19 s23 s23 s18 s19 s21 s22 s15 OR2 CO + 3H2OCO2 + 2H3O+ + 2e- Figure 59: Water-Gas Shift Reaction Reaction Route Graph 4. Overall graph It can be seen that step 12 is the same for both overall reactions. It appears in each mechanism to balance the overall reaction. If the two reactions are linked together in an overall graph for methanol electro-oxidation, adsorbed CO reacts directly and thus no desorption can occur. Consequently CO adsorption steps cancel each and the end of the methanol decomposition graph correspond to the beginning of the WGSR graph. However, three steps containing COHS as an intermediate remain (S24, S25, S26). They : Terminal Node : Intermediate Node - 89 -

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