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Electrolysis of CO2 and H2O

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Electrolysis of CO2 and H2O ( electrolysis-co2-and-h2o )

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Chapter 2. Replacing Petroleum with Sustainable Energy Carriers 36 carrier are meaningless. That a solar-to-hydrocarbon conversion may be only 10% efficient and a coal-to-hydrocarbon conversion may be 60% efficient does not mean that the latter is a six times better use of energy – it is a different type of energy with different supply. Another common metric used in life cycle analyses is the net greenhouse gas emissions that arise from all stages of the life-cycle of a product or energy conversion system – e.g. the construction, operation and maintenance. Such estimates are of course tied to a specific region and time. Taking photovoltaics (PV) as an example, every time a PV power plant is installed, the analysis becomes outdated – if PV were to scale up and comprise a significant fraction of electricity generation, the life-cycle greenhouse gas emissions of producing new PV panels would be much lower because more of the electricity used for producing the PV would come from PV itself. The methods used here emphasize looking at many aspects of the energy systems to assess sustainability and practicality. Such thorough examination using a multitude of metrics seems to be necessary and should lead to more useful assessments than studies that focus on providing a single value ―score‖ for a given energy technology or conversion pathway. 2.7. References 1. Lackner KS, A Guide to CO2 Sequestration. Science, (2003). 300(5626): p. 1677-1678. 2. EIA. Basic petroleum Statistics October 25, 2007]; Available from: h t t p : / / w w w . e i a . d o e . g o v / n e i c / q u i c k fa c t s / q u i c k o i l . h t m l . 3. IEA. World Oil Statistics for 2006. March 1, 2009]; Available from: http://www.iea.org/Textbase/stats/oildata.asp?COUNTRY_CODE=29. 4. Hill J, Nelson E, Tilman D, Polasky S, and Tiffany D, Environmental, economic, and energetic costs and benefits of biodiesel and ethanol biofuels. Proceedings of the National Academy of Sciences of the United States of America, (2006). 103(30): p. 11206-11210. 5. Rydh CJ and Sanden BA, Energy analysis of batteries in photovoltaic systems. part II: Energy return factors and overall battery efficiencies. Energy Conversion and Management, (2005). 46(11-12): p. 1980- 2000. 6. Farrell AE, Plevin RJ, Turner BT, Jones AD, O'Hare M, and Kammen DM, Ethanol can contribute to energy and environmental goals. Science, (2006). 311(5760): p. 506-508. 7. Climate Change 2001: IPCC Third Assessment Report. (2001), Intergovernmental Panel on Climate Change. 8. Yegulalp TM, Lackner KS, and Ziock H-J, A review of emerging technologies for sustainable use of coal for power generation. The International Journal of Surface Mining, Reclamation, and Environment, (2001). 15: p. 52-68. 9. Lackner KS, Can fossil carbon fuel the 21st century? International Geology Review, (2002). 44(12): p. 1122-1133. 10. Keith DW, DeCarolis JF, Denkenberger DC, Lenschow DH, Malyshev SL, Pacala S, et al., The influence of large-scale wind-power on global climate. Proceedings of the National Academy of Sciences, (2004). 101: p. 16115-16120. 11. King CW and Webber ME, Water Intensity of Transportation. Environmental Science & Technology, (2008). 42(21): p. 7866-7872.

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