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Chapter 3. Sustainable Hydrocarbon Fuels by Recycling CO2 with Renewable/Nuclear Energy 47 difficult materials requirements, overly tight design constraints, and lower flexibility in operation than using a larger number of steps with each step optimized for its particular function. This will be further discussed in section 3.2.2. Figure 3-3. Map of the possible pathways from H2O and CO2 to hydrocarbon fuels. ―Fischer Tropsch‖ represents any of a variety of catalytic fuel synthesis processes similar to the original Fischer-Tropsch processes. Following is a review of work that considers the entire cycle. The concept of CO2-recycled synthetic hydrocarbon fuels is not new. Likely spurred by the oil crisis of the 1970s, Steinberg and Dang [4-8] first envisioned the closed-loop version of CO2-recycled synthetic fuels with CO2 captured from ambient air. In a series of journal articles and patents, they explored various options to capture CO2 from the atmosphere using hydroxide or carbonate absorbents, produce H2 by water electrolysis, and synthesize methanol by reaction of the CO2 with H2, with nuclear fission or fusion supplying the electricity and heat. They proposed using the nuclear power plant cooling tower as part of the air capture absorption system. They also considered stripping CO2 from sea water, and using exhaust CO2 from industrial plants. Lewis and Martin [9] patented a similar process but with a thermally driven rather than electrically driven CO2 air capture absorbent regeneration cycle. A similar nuclear powered synthetic fuel process was outlined by Corbett and Salinas [10] followed by itsPDF Image | Electrolysis of CO2 and H2O
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