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Chapter 5. Aspects of Metal-YSZ Electrode Kinetics 126 Figure 5-11. Examples of gas partial pressure dependencies of LSRP of the various metal electrodes. The dashed lines are linear regressions; the slope of these lines corresponds to m in equation (5.1) and Table 5-3. Table 5-3. Gas partial pressure dependencies of LSRP at 850 °C, using equation (5.1). The pO2 dependences for the fixed pH2O and fixed pH2 variations are equal to the m values listed for pH2m and pH2Om multiplied by factors of -1 and 1⁄2 respectively. Since R2 regression coefficients for near-zero slopes (m values) are meaningless, they are not shown. Some of the gas variations included only 3 data points, so the statistical significance may not be as high as implied by the high R2 values. Metal Fixed pO2: m, in pH2Om and pH2m R2 Fixed pH2O: m, in pH2m R2 Fixed pH2: m, in pH2Om R2 Fixed pCO2: m, in pCOm R2 Cu Ni -0.45 -0.61 1.000 0.969 0.17 0.02 0.967 - -0.46 -0.63 0.963 0.997 0.01 -0.24 - 0.993 Pd -0.46 0.983 -0.10 0.998 0.07 0.947 -0.76 0.984 Pt -0.54 1.000 0.00 - -0.57 0.994 -0.14 0.974PDF Image | Electrolysis of CO2 and H2O
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