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Chapter 5. Aspects of Metal-YSZ Electrode Kinetics 160 Figure 5-38. SEM micrographs of the (a, b and d) YSZ surface at the edge of the contact area of a Ni electrode which had been subjected to a strong cathodic polarization. (c) The surface of the Ni wire that had been in contact with the YSZ surface. The Ni particle belt described previously had formed on the smooth polished YSZ surface outside the contact area, and the subsequent SCP formed Ni-zirconia composite nanostructures. Altogether the effects of strong cathodic polarization seem to make the point-contact electrodes more similar to cermet electrodes with fine microstructure – the nearly linear polarization curves are observed for fine-structured Ni-YSZ cermets, and the activation energy observed after strong cathodic polarization of the Ni point electrode is similar to that of fine Ni-YSZ cermets as well. However, the nanostructures resulting from reactivity between the metal and the reduced YSZ should not be present in cermets that were not subjected to strong cathodic polarization, so one possibility for the linearity for fine cermets is that there are fewer impurities. This will be further discussed in the next section 5.4. In regards to the nanostructures, during this study another research group performed strong cathodic polarization –2000 mV on a full cell with a Ni-YSZ cermet negative electrode and observed a decrease in the polarization resistance [80]. That study is still underway, but according to thePDF Image | Electrolysis of CO2 and H2O
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