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The E-CEM in Figure 1 uses direct current (DC) to exchange sodium ions (Na+) for H+ ions in a central stream that is flowing adjacent to two cation exchange membranes. Seawater is passed through the center compartment of the three compartment cell. Na+ ions are transferred through the membrane closest to the cathode and removed from the seawater by means of direct current (DC) voltage. These Na+ ions are replaced by H+ ions as the current drives the ions through the membrane closest to the anode to acidify the seawater. Table 1. E-CEM Configuration Dimensions Approximate Overall Cell Dimension Center Compartment Width Center Compartment Height Center Compartment Thickness Center Compartment Volume Membranes Active Area Each Electrode Compartment Volume Electrode Active Area Max. Current Density Max. Seawater Flow Rate Operating Seawater Flow Rate Max. RO Electrolyte Flow Rate Operating RO Flow Rate Max. Operating Temperature Max. Operating Pressure Anode Cathode Membrane Molded Frame and End Block 33 cm x 61 cm x 16 cm 14 cm 35.5 cm 0.90 cm 447 cm3 497 cm2 14.4 cm3 (each) Electrical Specification 497 cm2 (each) 1,500 A m-2 3900 mL/min 1900 mL/min 2100 mL/min 230 mL/min 60 oC 350 kPa Platinized Titanium Platinized Titanium Ionpure Cation-Permeable Membrane Polyethylene (PE) Flow Specification Materials In the cell, the anolyte is the water fed to the anode compartment. At the anode H+ is generated and it must migrate from the surface of the anode, through the cation-permeable membrane, and into the center compartment where it replaces Na+. Therefore the anolyte was diluted such that H+ ions are in excess and do not compete with any other cations. 4PDF Image | Extraction CO2 H2 in Seawater Electrolytic Cation Exchange
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