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( 1/4moleO2 )(60sec) 0.000155moleO2 96,487A-sec min A-min ( 1mole H )( 60sec) 0.000622 mole H 96,487A-sec min A-min Cathode Reaction ( 1/2moleH2 )(60sec) 0.000311moleH2 96,487A-sec min A-min (9) (10) (11) ( 1moleOH )(60sec) 0.000622moleOH (12) 96,487A-sec min A-min Therefore, for seawater with a bicarbonate (HCO3-) ion concentration of 142 ppm (0.0023 M) at a planned operating flow rate of 0.5 gal/min (1900 mL/min), a theoretical applied current of 7.0 amps will be required to lower the pH to less than 6.0 and convert HCO3- to carbonic acid (H2CO3) (equation 13). (0.0023 moleHCO3 )(1.89 Liter) Liter min 7.0A (13) ( 0.000622 mole H ) A-min Removal efficiency can be defined as the ratio of the theoretical amount of CO2 removed to the actual amount of CO2 removed in the acidified seawater. The theoretical amount of CO2 that can be removed from the acidified seawater is 0.0023 moles per liter. Removal efficiencies are never 100 % and can range from 50 to 95 % based on various unit operating requirements. The overall removal of CO2 in these tests was measured to be approximately 92%. The amount of H2 gas generated at 7.0 A is ( 1/2moleH2 )(60sec)(7.0A) 0.0022moleH2 (14) 96,487 A - sec min min Under these conditions, the molar ratio of H2 to CO2 is 0.73. Increasing the current increases the molar ratio of hydrogen to carbon dioxide with no effect on the operation of the module. H+ 6PDF Image | Extraction CO2 H2 in Seawater Electrolytic Cation Exchange
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