Extraction CO2 H2 in Seawater Electrolytic Cation Exchange

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Extraction CO2 H2 in Seawater Electrolytic Cation Exchange ( extraction-co2-h2-seawater-electrolytic-cation-exchange )

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C11H24 that could theoretically be produced in this apparatus is 0.03 gallons/day (2 x 10-5 gallons/minute or 4.5 mL/hour). The E-CEM was operated at a recovery of 81%. The term “recovery” is used to define the ratio of product quantity (influent seawater flow rate, Table 2) over the total feed quantity to the cell (influent seawater flow rate and influent deionized flow rate, Table 2) as a percent. A high recovery allows the size of the filtration unit along with the energy requirements for the unit to be minimized. This high recovery is possible due to the RO system and the ability to change the polarity of the electrodes in efforts to reduce scaling on the electrodes from hardness ions. 5.2 Carbon Dioxide and Hydrogen Gas Analysis A UIC Coulometric system (UIC Inc, Joliet, IL 60436) [12] was used to measure the [CO2]T content of the seawater throughout these tests. The [CO2]T content of the seawater before acidification was measured to be approximately 100 mg/L. A Honeywell 7866 digital gas analyzer with a thermal conductivity detector was used to measure the amount of H2 gas from the stripper column throughout the different tests. 5.3 Seawater pH The seawater pH was monitored continuously using a standard combination electrode as it exits the CO2 center compartment of the cell. The seawater pH changes as a function of current applied to the E-CEM. 5.4 SAFETY Safety is paramount in all field operations. Since hydrogen was produced during these test series, it was constantly diluted with air below its lower flammability and explosive limit. 6.0 RESULTS AND DISCUSSION The NRL team operated the E-CEM carbon capture skid to evaluate, measure, and optimize the system’s performance using KW-city water in the electrode compartments. This analysis concentrates on the E-CEM performance during two separate evaluations (February and April of 2017) as a function of current density, pH, time, polarity reversal, and E-CEM effluent discharge pH, anode effluent chlorine content, cathode effluent pH, and E-CEM process electrical efficiency. These data provide insight towards identifying and mitigating any environmental challenges that could arise during operation of NRL’s future prototype E-CEM that will process over 25 gpm of seawater at the NRL-KW facility. 6.1 E-CEM Effluent Discharge and Performance Several experiments were performed to characterize the combined effluent and individual effluent streams (anolyte, seawater, and catholyte) from operation of the E-CEM carbon capture skid under various operating conditions using RO and KW-city water in the electrode compartments. 11

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