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Extraction CO2 H2 in Seawater Electrolytic Cation Exchange

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Extraction CO2 H2 in Seawater Electrolytic Cation Exchange ( extraction-co2-h2-seawater-electrolytic-cation-exchange )

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6.1.1 E-CEM Performance and Effluent pH as a Function of Electrode Water Source Figure 5 compares the pH profiles of six polarity cycles as a function of time and current density (612, 408, 204 Amps/cm2) using RO (closed symbols) and KW-city water (open symbols) in the electrode compartments. The figure shows that as previously reported the pH takes longer to fall below 6 as the applied current is decreased to the E-CEM. When 408 Amps/cm2 of current density is applied to the module using KW-city water in the electrode compartments, the pH of the effluent seawater is still above 4.5 after twenty minutes of operation. At pH of 4.5 and below all the bicarbonate and carbonate in the seawater exist as carbonic acid and can be removed as CO2 gas [12]. 10 8 6 4 2 0 0 10 20 30 40 50 60 Time (minutes) Figure 5. A pH profile comparison for 6 polarity cycles measured at different applied current densities of, 612 Amps/m2 20 minute cycle, polarity A (●) RO electrode water source and polarity B (○) KW-city water electrode water source; 408 Amps/m2 30 minute cycle, polarity A (■) RO and polarity B (□) KW-city water; 204 Amps/m2 60 minute cycle, polarity A(▲) RO and polarity B () KW-city water. When the electrode water is switched to RO the pH of the seawater reaches 2.97 in five minutes. This figure shows a difference in E-CEM performance between the cycles using RO water and 12 pH

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