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Fuel Cell Handbook (Seventh Edition)

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Fuel Cell Handbook (Seventh Edition) ( fuel-cell-handbook-seventh-edition )

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the carbon pores by carbonate crystals. Improved electrodes can withstand even high amounts of CO2 (5 percent) over many thousands of hours, as proven recently by DLR (Deutsches Zentrum fuer Luft- und Raumfahrt) (26). Figure 4-7 Degradation in AFC Electrode Potential with CO2 Containing and CO2 Free Air Source: Figure 2, p. 381, Reference (25) High concentrations of KOH are also detrimental to the life of O2 electrodes operating with CO2- containing air, but operating the electrode at higher temperature is beneficial because it increases the solubility of CO2 in the electrolyte. Hence, modifying the operating conditions can prolong electrode life. Extensive studies by Kordesch, et al. (25) indicate that the operational life of air electrodes (PTFE-bonded carbon electrodes on porous nickel substrates) with CO2-containing air in 9N KOH at 65 °C ranges from 1,600 to 3,400 hours at a current density of 65 mA/cm2. The life of these electrodes with CO2-free air tested under similar conditions ranged from 4,000 to 5,500 hours. It was reported (2) that a lifetime of 15,000 hours was achieved with AFCs, with failure caused at that time by corrosion of the cell frames. 4.2.4 EffectsofCurrentDensity As in the case with PAFCs, voltage obtained from an AFC is affected by ohmic, activation, and concentration losses. Figure 4-8 presents data obtained in the 1960s (22) that summarizes these effects, excluding electrolyte ohmic (iR) losses, for a catalyzed reaction (0.5 to 2.0 mg noble metal/cm2) with carbon-based porous electrodes for H2 oxidation and O2 reduction in 9N KOH at 55 to 60 °C. The electrode technology was similar to that employed in the fabrication of PAFC electrodes. 4-12

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