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Fuel Cell Handbook (Seventh Edition)

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Fuel Cell Handbook (Seventh Edition) ( fuel-cell-handbook-seventh-edition )

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Table 7-1 Evolution of Cell Component Technology for Tubular Solid Oxide Fuel Cells Component Ca. 1965 Ca. 1975 At Present a Anode • Porous Pt • Ni/ZrO2 cermeta • Ni/ZrO2 cermetb • Deposit slurry, EVD fixedc • 12.5 X 10-6 cm/cm °C CTE • ~150 μm thickness • 20 to 40 percent porosity Cathode • Porous Pt • Stabilized ZrO2 impregnated with praseodymium oxide and covered with SnO doped In2O3 • Doped lanthanum manganite • Extrusion, sintering • ~2 mm thickness • 11 X 10-6 cm/cm °C CTE from room temperature to 1000 °C • 30 to 40 percent porosity Electrolyte • Yttria stabilized ZrO2 • 0.5-mm thickness • Yttria stabilized ZrO2 • Yttria stabilized ZrO2 (8 mol percent Y2O3) • EVDd • 10.5 X 10-6 cm/cm °C CTE from room temperature to 1000 °C • 30 to 40 μm thickness Cell Interconnect • Pt • Mn doped cobalt chromite • Doped lanthanum chromite • Plasma spray • 10 X 10-6 cm/cm °C CTE • ~100 μm thickness a - Specification for Siemens Westinghouse SOFC b - Y2O3 stabilized ZrO2 c - “Fixed EVD” means additional ZrO2 is grown by EVD to fix (attach) the nickel anode to the electrolyte. This process is expected to be replaced. d - EVD = electrochemical vapor deposition The cell interconnect (doped lanthanum chromite) must be impervious to fuel and oxidant gases, and must possess good electronic conductivity. The interconnect is exposed to both the cathode and anode environments. Thus, it must be chemically stable under O2 partial pressures of about 1 to 10-18 atmospheres at 1,000 °C. The interconnect material is applied to the cathode tube as a narrow strip (see Figure 7-9, Figure 7-11) prior to depositing the electrolyte by masking the rest of the tube. Similarly, the interconnect strip is masked when the electrolyte is applied. The other cell components should permit only electronic conduction, and interdiffusion of ionic species in these components at 1,000 °C should not affect their electronic conductivity. Other restrictions on the cell components are that they must be stable in the gaseous environments in the cell and they must be capable of withstanding thermal cycling. The materials listed in Table 7-1 appear to meet these requirements. 7-17

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