PDF Publication Title:
Text from PDF Page: 017
Catalysts 2021, 11, 482 17 of 19 References calculated from Auger parameter values on the surface of the CuZnAl-oxide based catalysts, Figure S4: Determination of relative roughness (geometric area 0.0706 cm2) of Cu-06 catalyst, Figure S5: LSV responses under CO2 flow of CuZA-06-03-01 catalysts in a Rotating Disk Electrode System. The test was carried out in CO2-purged 0.1 M KHCO3 electrolyte (scan rate: 5 mV s−1) with a catalyst loading of 0.6 mgCuO cm−2, Figure S6: CV responses for a electrode with a ink without catalyst nanoparticles. The VC/Nafion ratio was 70/30, and the test was carried out in 0.1 M KHCO3 aqueous electrolyte, Figure S7: Faradaic efficiencies of gas and liquid products at −1.5 V vs. Ag/AgCl for a electrode with a ink without catalyst nanoparticles. The chronoamperometry was carried out in 0.1 M KHCO3 aqueous electrolyte, Figure S8: Schematic of the control volume, Figure S9: Surface pH trends obtained with the developed model: reproduction of the data reported by Lv et al. and processing of our experimental data (green curve) (obtained with tests conducted on Cu-06 catalyst at −1.5, −1.75 and −2 V vs. Ag/AgCl in 1 M KHCO3 electrolyte solution), Figure S10: Influence of the catalyst thickness on the calculated surface pH for a specific test, conducted on Cu-06 catalysts at −1.5 V vs. Ag/AgCl in 1 M KHCO3 electrolyte solution, Table S1: CO2 reduction products and corresponding standard reduction potential (E0) vs. Normal Hydrogen Electrode (NHE) at pH = 0, Table S2: Main textural parameters of the synthesized CuZnAl-oxide based catalysts, Table S3: Crystallite sizes of the synthesized CuZnAl-oxide based catalysts, Table S4: Capacitance and ECSA values of the electrodes, Table S5: Effective and bulk diffusion coefficients of chemical species in the bulk electrolyte at 25 ◦C, Table S6: Rate constants for forward and reverse reaction at 25 ◦C. Author Contributions: Data curation, Investigation and Writing—original draft, H.G. and F.Z.; Catalysts synthesis, D.R. and H.G.; XRD and ICP analyses, C.G. and H.G.; Methodology, H.G., F.Z. and S.H.; Modelling, F.Z.; Funding acquisition, S.H.; Supervision and Resources, N.R. and S.H.; Writing—review & editing, H.G., F.Z. and S.H. All authors have read and agreed to the published version of the manuscript. Funding: This research was funded by European Union’s Horizon 2020 Research and Innovation Action programme under the SunCoChem project, Grant Agreement No 862192, and the Piedmont Region project Saturno (https://saturnobioeconomia.it (accessed on 6 April 2021)). Acknowledgments: The authors are thankful to Mauro Raimondo and Micaela Castellino for the technical support in the acquisition of FESEM images and XPS data, respectively. Conflicts of Interest: The authors declare no conflict of interest. 1. Guzmán, H.; Salomone, F.; Batuecas, E.; Tommasi, T.; Russo, N.; Bensaid, S.; Hernández, S. How to make sustainable CO2 conversion to Methanol: Thermocatalytic versus electrocatalytic technology. Chem. Eng. J. 2020, 127973. [CrossRef] 2. Jouny, M.; Luc, W.W.; Jiao, F. General Techno-Economic Analysis of CO2 Electrolysis Systems. Ind. Eng. Chem. Res. 2018, 57, 2165–2177. [CrossRef] 3. Vennekoetter, J.-B.; Sengpiel, R.; Wessling, M. Beyond the catalyst: How electrode and reactor design determine the product spectrum during electrochemical CO2 reduction. Chem. Eng. J. 2019, 364, 89–101. [CrossRef] 4. Endro ̋di, B.; Bencsik, G.; Darvas, F.; Jones, R.; Rajeshwar, K.; Janáky, C. Continuous-flow electroreduction of carbon dioxide. Prog. Energy Combust. Sci. 2017, 62, 133–154. [CrossRef] 5. Burdyny, T.; Smith, W.A. CO2 reduction on gas-diffusion electrodes and why catalytic performance must be assessed at commercially-relevant conditions. Energy Environ. Sci. 2019, 12, 1442–1453. [CrossRef] 6. Sacco, A.; Zeng, J.; Bejtka, K.; Chiodoni, A. Modeling of gas bubble-induced mass transport in the electrochemical reduction of carbon dioxide on nanostructured electrodes. J. Catal. 2019, 372, 39–48. [CrossRef] 7. Raciti, D.; Mao, M.; Wang, C. Mass transport modelling for the electroreduction of CO2 on Cu nanowires. Nanotechnology 2017, 29, 044001. [CrossRef] [PubMed] 8. Singh, M.R.; Clark, E.L.; Bell, A.T. Effects of electrolyte, catalyst, and membrane composition and operating conditions on the performance of solar-driven electrochemical reduction of carbon dioxide. Phys. Chem. Chem. Phys. 2015, 17, 18924–18936. [CrossRef] [PubMed] 9. Schouten, K.J.P.; Gallent, E.P.; Koper, M.T. The influence of pH on the reduction of CO and CO2 to hydrocarbons on copper electrodes. J. Electroanal. Chem. 2014, 716, 53–57. [CrossRef] 10. Ooka, H.; Figueiredo, M.C.; Koper, M.T.M. Competition between Hydrogen Evolution and Carbon Dioxide Reduction on Copper Electrodes in Mildly Acidic Media. Langmuir 2017, 33, 9307–9313. [CrossRef] 11. Guzmán, H.; Russo, N.; Hernández, S. CO2 valorisation towards alcohols by Cu-based electrocatalysts: Challenges and perspectives. Green Chem. 2021, 23, 1896–1920. [CrossRef]PDF Image | Gas Diffusion Electrode Systems for the Electro CO2 Conversion
PDF Search Title:
Gas Diffusion Electrode Systems for the Electro CO2 ConversionOriginal File Name Searched:
catalysts-11-00482.pdfDIY PDF Search: Google It | Yahoo | Bing
NFT (Non Fungible Token): Buy our tech, design, development or system NFT and become part of our tech NFT network... More Info
IT XR Project Redstone NFT Available for Sale: NFT for high tech turbine design with one part 3D printed counter-rotating energy turbine. Be part of the future with this NFT. Can be bought and sold but only one design NFT exists. Royalties go to the developer (Infinity) to keep enhancing design and applications... More Info
Infinity Turbine IT XR Project Redstone Design: NFT for sale... NFT for high tech turbine design with one part 3D printed counter-rotating energy turbine. Includes all rights to this turbine design, including license for Fluid Handling Block I and II for the turbine assembly and housing. The NFT includes the blueprints (cad/cam), revenue streams, and all future development of the IT XR Project Redstone... More Info
Infinity Turbine ROT Radial Outflow Turbine 24 Design and Worldwide Rights: NFT for sale... NFT for the ROT 24 energy turbine. Be part of the future with this NFT. This design can be bought and sold but only one design NFT exists. You may manufacture the unit, or get the revenues from its sale from Infinity Turbine. Royalties go to the developer (Infinity) to keep enhancing design and applications... More Info
Infinity Supercritical CO2 10 Liter Extractor Design and Worldwide Rights: The Infinity Supercritical 10L CO2 extractor is for botanical oil extraction, which is rich in terpenes and can produce shelf ready full spectrum oil. With over 5 years of development, this industry leader mature extractor machine has been sold since 2015 and is part of many profitable businesses. The process can also be used for electrowinning, e-waste recycling, and lithium battery recycling, gold mining electronic wastes, precious metals. CO2 can also be used in a reverse fuel cell with nafion to make a gas-to-liquids fuel, such as methanol, ethanol and butanol or ethylene. Supercritical CO2 has also been used for treating nafion to make it more effective catalyst. This NFT is for the purchase of worldwide rights which includes the design. More Info
NFT (Non Fungible Token): Buy our tech, design, development or system NFT and become part of our tech NFT network... More Info
Infinity Turbine Products: Special for this month, any plans are $10,000 for complete Cad/Cam blueprints. License is for one build. Try before you buy a production license. May pay by Bitcoin or other Crypto. Products Page... More Info
CONTACT TEL: 608-238-6001 Email: greg@infinityturbine.com (Standard Web Page)