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Materials 2021, 14, 1617 16 of 20 freestanding PEM delivers improved proton conductivity and alcohol resistance (with respect to Nafion 117) in addition to promising mechanical properties. The hydrophobic AN-co-GMA to the hydrophilic SPA ratio was an important structural parameter as it determines both proton conductivity and fuel permeability of the membrane. An optimal hydrophobic/hydrophilic ratio in the ionomer leads to a balance amidst all the requisite PEM properties. The swelling and dimensional stability of the cross-linked diblock ionomer membranes depend not only on polymer composition and hence the ionomer structure, but also the type of alcohol solutions (methanol or ethanol). Author Contributions: Conceptualization, D.J., J.Y.L. and L.H.; methodology, D.J.; validation, L.H. and J.Y.L.; formal analysis, L.H.; investigation, D.J.; resources, J.Y.L. and L.H.; writing—original draft preparation, D.J.; writing—review and editing, J.Y.L. and L.H.; visualization, L.H.; supervision, J.Y.L. and L.H.; project administration, J.Y.L.; funding acquisition, J.Y.L. All authors have read and agreed Materials 2021, 14, x FOR PEER REVIEW 1 to the published version of the manuscript. Funding: This research received no external funding. Institutional Review Board Statement: Not applicable. Informed Consent Statement: Not applicable. Informed Consent Statement: Not applicable. Data Availability Statement: Excluded. Data Availability Statement: Excluded. Conflicts of Interest: The authors declare no conflict of interest. Conflicts of Interest: The authors declare no conflict of interest. Appendix A Appendix A SEM-images to show the micro-morphologies of the membranes prepared. SEM-images to show the micro-morphologies of the membranes prepared. Figure A1. FE-SEM images of cross-linked diblock A50G4S-10 membrane (magnification 50,0 Figure A1. FE-SEM images of cross-linked diblock A50G4S-10 membrane (magnification 50,000×).PDF Image | Hydrophilic Cross-Linked Aliphatic Hydrocarbon Diblock Copolymer
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