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Results and discussion loading 2.0 mg/cm2 of catalyst for anode and cathode (which is double the amount of catalyst loading used in this work) when operating the fuel cell 70°C and 1.0 M methanol. Rhee et al [171] found the fuel cell power density was ~ 50 mW/cm2 at 2.0 M methanol concentration with a catalyst loading of 8 mg/cm2 for both anode and cathode using a fuel cell active area of 10 cm2. Jiang et al [142] loaded their anode and cathode with 2.5 mg/cm2 of catalyst. They obtained a maximum fuel cell power density of 51 mW/cm2 at 65°C and 1.0 M methanol concentration. Dohle et al [172] found the maximum power density of DMFC at 70°C and 1.0 M was 50 mW/cm2 by using anodic catalyst loading of 3.9 mg/cm2 and cathodic catalyst loadings of 2.3 mg/cm2 . In this work, the catalyst loading was 1.0 mg/cm2 for all fabricated electrodes and the optimum fuel cell temperature and concentration was 70°C and 1.0 M respectively. These values were chosen to be the base line of all the following DMFC experiments. This makes a comparison between mordenite MEA and GO MEA with standard MEA. All four MEAs including standard MEA, F-MOR MEA, SULFO-MOR MEA, and GO MEA showed high fuel cell performance (power density) at 70°C. The fuel cell operating temperature has its own advantages and disadvantage. The advantage of increasing the fuel cell operating temperature (40°C to 70°C) is that the power density reached peak at higher temperature. The rise in the power density resulting from increasing the temperature may attribute to the reaction kinetics at the surface of the electrode which helps the oxidation of methanol at the anode. The more oxidation of methanol at the anode the less mix potential at the cathode thus, higher fuel cell performance. Increasing the fuel cell temperature can also ease the transport of the reactants toward the electrodes [173]. Moreover, increasing the fuel cell temperature reduce the ohmic resistance of the membrane thus increases the fuel cell performance [27]. On the other hand, the disadvantage of increasing the fuel cell temperature has its own effect on the open circuit voltage at the cathode side. Also, when increasing the fuel cell temperature methanol crossover from the anode toward the cathode increased. Increasing the temperature increases the methanol crossover by expanding the flow channels in the membrane due to swelling effects of the membrane and also increases the mass transfer loss at higher current density. This behaver was seen in all three Sirhan AL-Batty Page 144PDF Image | Membrane Electrode Assembly Modification by Zeolite and Graphene Oxide
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