Recycling of carbon dioxide to produce ethanol

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Recycling of carbon dioxide to produce ethanol ( recycling-carbon-dioxide-produce-ethanol )

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6686 Youness El Fouih and Chakib Bouallou / Energy Procedia 37 (2013) 6679 – 6686 3.5 t of CO2 and 5 t of H2O to produce 1 ton of ethanol, which means that more than 21 000 t of CO2 and 300 000 t of water vapor are consumed each year. The total primary energy consumption rises to 109.8 MJ per 1 kg of ethanol, which is more than the energy consumption of the usual ethanol production processes. Due to lack of experience feedback, the economic analysis of the whole process was carried out using cost estimating assumptions based on pilot plant costs and similar processes costs. The results of the economic analysis demonstrated that the ethanol production plant driven by a high-temperature nuclear power plant can deliver ethanol at a cost of $1.1/kg, assuming an internal rate of return on investment of 8%. This final cost could be lowered if we consider the co-production of methane and hydrogen. Also, if we take into account oil price increase and the subsidies it is estimated that this process can be competitive with other conventional methods of producing ethanol in the next 10 to 15 years. References [1] Thybaud N, Lebain D. Overview of CO2 recycling pathways, ADEME Jun 2010, p. 16 22. [2] Graves C, Ebbesen S D, Mogensen M, Lackner K S. Sustainable hydrocarbon fuels by recycling CO2 and H2O with renewable or nuclear energy. Renewable and Sustainable Energy Reviews 2011; 15:1 23. [3] Subramani V, Gangwal SK. A review of recent literature to search for an e catalytic process for the conversion of syngas to ethanol. Energy & Fuels 2008; 22: 814 839. [4] Graves C, Ebbesen SD, Mogensen M. Co-electrolysis of CO2 and H2O in solid oxide cells : Performance and durability. Solide State Ionic. 2010; 192:398 403. [5] Hawkes G, O'Brien J, Stoots C, Hawkes B. 3D CFD model of a multi-cell high-temperature electrolysis stack. International Journal of Hydrogen Energy 2009; 34: 4189 4197. [6] Stootsa CM, O'Briena JE, Condiea KJ, Hartvigsen JJ. High-temperature electrolysis for large- scale hydrogen production from nuclear energy : Experimental investigations. International Journal of Hydrogen Energy 2010, 35: 4861 4870. [7] McKellar MG, Sohal MS, Sohal CM, Mulloth L, Luna B, Abney MB. Mathematical analysis of high-temperature co-electrolysis of CO2 and O2 production in a closed-loop atmosphere revitalization system. March 2010. [8] Spath P, Dayton D. Technical and Economic Assessment of Synthesis Gas to Fuels and Chemicals with Emphasis on the Potential for Biomass-DeriVed Syngas. National Renewable Energy Laboratory. 2003. [9] Xu BQ, Sun KQ, Zhu QM, Sachtler WM.H. Unusual selectivity of oxygenate synthesis: Formation of acetic acid from syngas over unpromoted Rh in NaY zeolite. Catalysis Today 2000; 63: 453 460 [10] Subramanian ND, Gao J, MoX , Goodwin JG., Torres W, Spivey JJ. La and/or V oxide promoted Rh/SiO2 catalysts: Effect of temperature, H2/CO ratio, space velocity, and pressure on ethanol selectivity from syngas. Journal of Catalysis 2010; 272 : 204 209 [11] Herman RG. Advances in catalytic synthesis and utilization of higher alcohols. Catalysis Today 2000;55:233 245. [12] Gil ID, Uyazan AM, Aguilar JL, Rodriguez G, Caicedo LA. Separation of ethanol and water by extractive distillation with salt and solvent as entrainer : Process simulation. Brazilian Journal of Chemical Engineering 2008;25:207-215. [13] Perez-Blanco H, Hannon B. Net energy analysis of methanol and ethanol production. Energy 1982; 7: 267-280. [14] Jensen JO, Jensen SH, Tophøj N. Pre-investigation of water electrolysis. 2008.

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