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Patel and Patel | 5 Downloaded from https://academic.oup.com/ce/advance-article-abstract/doi/10.1093/ce/zkx008/4743500 by guest on 15 December 2017 Table 3 Studies on steam reforming of butanol Catalyst Support Preparation method SCMR/ Temperature (°C), SBMR pressure (kPa) CCGP% Yield of hydrogen Selectivity of hydrogen Reference Ni (20 wt.%)/Al2O3 Ni (20% wt.%)/CeO2 NiAl (Ni-28.5 wt.%) NiAlMg0.26 (Ni-29.3 wt.%, Mg/Al molar ratio 0.26) NiAlCa0.12 (Ni-26.3 wt.%, Ca/Al molar ratio 0.12) ImpNiAlCa0.03 (Ni-7.5 wt.%, Ca/Al molar ratio 0.03) Ni (28% expressed as Ni/(Ni+Al)) relative atomic weight Ni (23% expressed as Ni/(Ni+Al)) relative atomic weight Ni (33% expressed as Ni/(Ni+Al)) relative atomic weight NiAl (30.1 wt.% Ni, 18.1 wt.% Al, 21.5 wt.% Mg, 0.1 wt.% Cu) NiAl (28.8 wt.% Ni, 16.7 wt.% Al, 20.6 wt.% Mg, 5.5 wt.% Cu) 4.3NiAl (4.3 mmol Ni per gram of γ-Al2O3) 4.3NiSi (4.3 mmol Ni per gram of SiO2) 4.3NiZr (4.3 mmol Ni per gram of ZrO2) 4.3CoAl (4.3 mmol Co per gram of γ-Al2O3) 4.3MoAl (4.3 mmol Mo per gram of γ-Al2O3) 25 NiAl (25 wt.% Ni on γ-Al2O3) 20 NiAl (20 wt.% Ni on γ-Al2O3) 10 NiAl (10 wt.% Ni on γ-Al2O3) Co/ZnO (7 wt.% Co) Co/CeO2 (7 wt.% Co) Co/TiO2 (7 wt.% Co) Rh (5 wt.%)/Al2O3 Ni (5 wt.%)/Al2O3 Al2O3 Solution combustion CeO2 Solution combustion — Co-precipitation — Co-precipitation 11.15H 215 °C, 1034 kPa 11.15H 215 °C, 1034 kPa 14.7I 650 °C, 101.3 kPa 14.7I 650 °C, 101.3 kPa 14.7I 650 °C, 101.3 kPa 14.7I 650 °C, 101.3 kPa 14.71I 650 °C, 101.3 kPa 14.71I 650 °C, 101.3 kPa 14.71I 650 °C, 101.3 kPa 14.7I 650 °C, 101.3 kPa 14.7I 650 °C, 101.3 kPa — — — — 97.34%D 0.3125G 97.41%D 0.3208G 96.49%D 0.3078G 44.42%D 0.1274G 82.76%D 0.291G 79.83%D 0.287G 82.02%D 0.283G 70.35%D 0.233G 45.81%D 0.148G ~98%D ~76%C ~88%D ~68%C ~40%D ~33%C ~86%D ~66%C ~36%D ~27%C 100%D 84.49%E 84.75%D 65.94%E 31.2%D 64.49%E 100% 73.4 mol% in outlet gas 100% 73.1 mol% in outlet gas 100% 72.3 mol% in outlet gas 100%K 62.9%F 100%K 55.2%F 30.8A [22] 48.2A — [40] — — Co-precipitation — Impregnation — Co-precipitation — Co-precipitation — Co-precipitation — Co-precipitation — Co-precipitation γ-Al2O3 Incipient wetness SiO2 Incipient wetness ZrO2 Incipient wetness γ-Al2O3 Incipient wetness γ-Al2O3 Incipient wetness γ-Al2O3 Wet impregnaton γ-Al2O3 Wet impregnaton γ-Al2O3 Wet impregnaton ZnO Incipient wetness CeO2 Incipient wetness TiO2 Incipient wetness α-Al2O3 Wet impregnation α-Al2O3 Wet impregnation impregnation impregnation impregnation impregnation impregnation 2.2H 650 °C, 101.3 kPa 2.2H 650 °C, 101.3 kPa 2.2H 650 °C, 101.3 kPa 2.2H 650 °C, 101.3 kPa 2.2H 650 °C, 101.3 kPa 2.49H 500 °C, 101.3 kPa 2.49H 500 °C, 101.3 kPa 2.49H 500 °C, 101.3 kPa 8I 600 °C, 101.3 kPa 8I 600 °C, 101.3 kPa 8I 600 °C, 101.3 kPa 9J 900 °C, 101.3 kPa 9J 900 °C, 101.3 kPa — — — [44] — — — [46] — — [47] — — — — — [48] — — — [30] — — — [5] — impregnation impregnation impregnationPDF Image | Renewable hydrogen production from butanol
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