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SOEC SOFC Figure 5. Temperature maps for cell in SOEC mode and SOFC mode of operation (Slide 41 from CERAMATEC presentation) As the last part of their presentation, CERAMATEC introduced the concept of CO2 beneficiation. The proposed process is the production of liquid fuels by feeding carbon dioxide and steam into the hydrogen side of the SOEC. Hydrogen, produced by electrolysis of the steam, reacts with the carbon dioxide while still in the cathode chamber to produce syngas, which is dominated by hydrogen and carbon monoxide. The syngas is then passed to a Fischer-Tropsch (F-T) reactor where it is used to produce hydrocarbon fuels. This process was proposed as an alternative to hydrogen as a means of storing renewable energy. Electrolysis Reaction: Cathode: Anode: Fischer-Tropsch Reaction: H2O+CO2 +4e−→H2 +CO+2O2− 2 O2− → O2 + 4e− (2n+1)H2 + nCO → H2n+2Cn + nH2O The F-T liquids can be substituted for petroleum-derived products. If the electricity supplied to the electrolyzer is from renewable sources, the hydrocarbon liquids would be considered a 100% renewable fuel. 21PDF Image | Reversible Fuel Cells Workshop Summary Report
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