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Zeolite Catalysis

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Zeolite Catalysis ( zeolite-catalysis )

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17 Reaction Reactor Type Feed Operating Conditions Table 1. Cont. Catalyst Membrane XCR (%) SCR (%) YCR (%) XMR (%) SMR (%) YMR (%) References m-xylene isomerization PBMR m-xylene diluted in helium HZSM-5 silicalite-1/ α-Al2O3 disc Sp-xylene = 44.6 - [161] m-xylene isomerization PBMR m-xylene, carrier gas: nitrogen 473–573 K sweep gas: nitrogen MFI/α-Al2O3 tube acid-functionalized silicalite-1/ α-Al2O3 Sp-xylene = 42 Yp-xylene = 27 Sp-xylene = 49 Yp-xylene = 23 [162,163] [164] [165] [166] xylene isomerization m-xylene diluted CMR in hydrogen 355–450 ◦C p = 101 kPa sweep gas: nitrogen disc propylsulfonic and arenesulfonic acid sites n.r. n.r. n.r. Xm-xylene = 52 Yp-xylene = 32 at m-xylene isomerization CMR m-xylene diluted in helium 270 ◦C weep gas: helium H-MFI/α-Al2O3 disc [B]MFI/α-Al2O3 tube 450 ◦C Xm-xylene = 6.5 Double-bond isomerization of 1-butene 1-butene diluted CMR in nitrogen 120–250 ◦C p = 1 bar sweep gas: nitrogen Sp-xylene = 92.1 X = 44.5 Esterification of ethanol with acetic acid ethanol, acetic CMR acid 333–363 K ∆p = 0–1 bar sweep gas: He H-ZSM-5/α-Al2O3 or stainless steel tubes X = 49.4 X = 63.1 [167] Esterification of acetic acid with ethanol ethanol, acetic PBMR acid 358 K pret = 1.3 bar pperm = 2 mbar Amberlyst 15 modernite/α-Al2O3 zeolite A/α-Al2O3 X = 66.9 X = ~90 [168] Catalytic dehydration of methanol PBMR methanol 150–250 ◦C WHSV= 0.5–2.6 h−1 pfeed = 1–1.7 bar pperm= 1 mbar γ-alumina NaA/stainless steel wire mesh XCH3OH = 61 at 230 ◦C XCH3OH = 85 at 230 ◦C [169] CO2 hydrogenation into methanol carbon dioxide, PBMR hydrogen 200–263 ◦C p = 20–24 bar H2/CO2 = 3–7 Cu/ZnO/Al2O3 NaA/α-Al2O3 tube XCO2 = 5 SCH3OH = 48 YCH3OH = 2.4 XCO2 = 11.6 SCH3OH = 75 YCH3OH = 8.7 [170] 270–390 ◦C sweep gas: helium diverse packing configurations GHSV = 1574 h−1 Xm-xylene = 51.9 Sp-xylene = 35.7 GHSV = 4722 h−1 Xm-xylene = 36.5 Sp-xylene = 47.3 - Xm-xylene = 47.8 Pt-HZSM-5 Xm-xylene = 36.1 Sp-xylene = 49.6 ratio trans/cis = 2.2 at 250 ◦C

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