Zeolite Catalysis

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Zeolite Catalysis ( zeolite-catalysis )

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xylene isomer separation, demonstrating the strong impact of the crystal orientation on the membrane performance for certain separation task and for future applications Catalysts 2015, 5 2185 in membrane reactors as well. Figure 7. ZSM-5 membrane performance in xylene isomer separation (feed Figure 7. ZSM-5 membrane performance in xylene isomer separation (feed partial pressure partial pressure of p-xylene and o-xylene are 0.45 kPa and 0.35 kPa, respectively): of p-xylene and o-xylene are 0.45 kPa and 0.35 kPa, respectively): p-xylene, o-xylene p-xylene, o-xylene permeance, and mixture separation factor (SP) in dependence permeance, and mixture separation factor (SP) in dependence on temperature for on temperature for (A) c-oriented; (B) [h0h]-oriented; (C) a- and b-oriented; and (A) c-or(iDen)tbe-do;rie(Bnt)ed[hfi0lmh]-[o22ri6e].nRtedp;ri(nCte)daw-itahnpderbm-oisrsieionntefdro;manAdA(ADS). b-oriented film [226]. Reprinted with permission from AAAS. Considering xylene isomerization in PBMRs, the extraction of the produced Considpe-rxiynlgenxeyflreonmetihsoemrearciztiaotinonzoinePviBaMzeRosli,tethmeeemxbtrraacntieowniollfshthifettphreodequuceildibpri-uxmyleanedfromthe ensure selectivity enhancement and higher p-xylene yields. reaction zone via zeolite membrane will shift the equilibrium and ensure selectivity enhancement and higher p-xylene yields. In this context, Zhang et al. [161] tested silicalite-1/α-Al2O3 zeolite membranes packed together with HZSM-5 catalysts in the isomerization of m-xylene to p-xylene, applying different packing methods: (i) by depositing the catalyst on the Al2O3 support on the opposite side of the membrane; and (ii) by packing it in the tube in contact with the membrane layer. The latter packing method turned out to be more 32 effective for the studied reaction since it gave rise to higher p-xylene yield and selectivity than in

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