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BIOMASS TO ENERGY AND CHEMICALS HighBio2 Project Publication

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BIOMASS TO ENERGY AND CHEMICALS HighBio2 Project Publication ( biomass-to-energy-and-chemicals-highbio2-project-publication )

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FIGURE 1. Gas solubilities in ILs. (a) Solubility of H2, CO2, and H2S in [C6mim] [Tf2N] at 333 K; (b) solubility of CO, CO2, and H2S in [C4mim][PF6] at 313 K. Symbols: experimental data (triangles: CO2; diamonds: H2S; circles: H2; squares: CO), curves: ePC-SAFT predictions. Experimental measurements for a novel IL In general, the synthesis of ILs is a complicated process, which increases costs and hinders the progress of research and development of practical applications. In recent years, deep eutectic solvent was proposed and considered to be a new type of IL. Among this type of IL, the solvent of choline chloride/urea has shown great potential to be used as liquid absorbents for CO2 separation due to, among other factors, its low cost, easy synthesis and bio-degradation. Several studies have been done, for example, on the CO2 solubility in choline chloride/urea as well as on its density and heat capacity. However, the available knowledge is limited regarding its application, and both new experimental data measurement and modeling need to be studied further, including on the solubility of other gases (e.g., CO2, N2, CO, CH4, and H2), diffusivity, density, viscosity, and more. In addition, it has been observed that some properties of choline chloride-based ILs considerably depend on the water content. The water effects on density, vapor pressure, and heat capacity have been studied, but the effects of water on other properties of choline chloride-based ILs have not yet been investigated. Further research is required. 71

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