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HIGHBIO2 PROJECT PUBLICATION from the gasifier is usually yellow and muddy, sometimes even dark. It contains some solid material that can be dissolved with organic solvents, such as DMSO (dimethylsulfoxide) and ethanol. Composition of pollutants in condensing water In order to identify the organic pollutants in condensing water from gasification processes, it was extracted for analysis by two different methods. First, the solution was diluted with DMSO and examined with gas chromatography mass spectrometry (GC-MS). Another extraction was done with 1,2-dichloroethane and both water and solvent phases were examined with GC-MS. The organic compounds found before any treatment of condensing water were small organic acids, phenols, phenantrene, anthracene, naphthalene, biphenylene, dibenzofuran, pyrene, fluorine, and their derivatives. After extraction the main components left in the condensing water were mainly phenols. Table 1 presents the metal contents of the condensing water and some limit values for sewage. Based on the results of the samples studied, the metal contents were not so high that they should be removed from the condensing water. TABLE 1. As Hg Ag Cd Cr Cu Pb Ni Zn Sn Typical metal contents of the raw condensing water sample and the average limit values for drainage. (Kouvolan Vesi) Metal limit value [mg/L] Metal measured value condensing water [mg/L] 0.1 0.01 0.2 0.01 1.0 2.0 0.5 0.5 3.0 2.0 <0.04 <0.5 [μg/L] Not measured <0.01 <0.03 0.06 <0.04 <0.02 0.04 <0.04 94PDF Image | BIOMASS TO ENERGY AND CHEMICALS HighBio2 Project Publication
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