BIOMASS TO ENERGY AND CHEMICALS HighBio2 Project Publication

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BIOMASS TO ENERGY AND CHEMICALS HighBio2 Project Publication ( biomass-to-energy-and-chemicals-highbio2-project-publication )

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were measured from these purified waters. The purification efficiency was the best with extraction by kerosene. Pentanol and hexanol were also good extractants. The pure motor oil was as good as others extactants, but there were three phases at the end. First was the water phase, second was a white solid material and third was an oil phase. The disposal of this phase was so difficult that motor oil was not used further. The others can be disposed of through burning. The result was that the motor oil, biodiesel, and rape seed oil all caused a water-oil emulsion in both phases. Diesel oil and fuel oil also were tested and the results were not as good as using kerosene extraction. FIGURE 3. Extracted condensing waters from wood chips from biogasification with kerosene (1 and 2), pentanol (3 and 4) and hexanol (5 and 6). Oxidation of samples by UV light and hydrogen peroxide The combination of UV (Ultra Violet) light and hydrogen peroxide were tested and the result was that it is not suitable as a purification method for these kinds of waters. The amount of hydrogen peroxide consumed was quite large and the flow rate was 200 ml/min. Discussion In the preliminary experiments, the activated carbon was the only functional treatment that gave clearly better results than the other tested treatment methods mentioned above. However, activated carbon filtration purified only a part of the organic matter. It was also the only treatment method that lowered all COD (chemical oxygen demand), DOC (dissolved organic carbon), and BOD (biological oxygen demand) values. After other 99

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