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Table 8 Variation in CO2 exit temperature with preheating in ORC for n-Butane. [2] Brasz J, Holdmann G. Power production from a moderate-temperature geothermal resource. Geothermal Resources Council Transactions 2005;29: 729e33. [3] The Future of Geothermal Energy. Impact of Enhanced Geothermal Systems (EGS) on the United States in the 21st Century. Massachusetts: Institute of Technology; 2006. p. 372. [4] Elsworth D. Theory of thermal recovery from a spherically stimulated hot dry rock reservoir. Journal of Geophysical Research: Solid Earth 1989;94(B2): 1927e34. [5] Sanyal SK, Butler SJ. An analysis of power generation prospects from enhanced geothermal systems. Geothermal Resources Council Transaction 2005;29. [6] Polsky Yarom, Capuano Jr Louis, Finger John, Huh Michael, Knudsen Steve, Chip Mansure AJ, et al. Enhanced Geothermal Systems (EGS) Well Construc- tion Technology Evaluation Report. Sandia National Laboratories; December 2008. p. 108. [7] Benzie S, Burge P, Dobson A. Towards a Moni-diameter well e advances in expanding tubular technology. Proc. SPE European Petroleum Conference 2000, SPE 65164, Paris, 2000. [8] Lohbeck WCM. Method of completing an uncased section of a borehole, United States Patent 5366012, 1993. [9] Aladeitan, Mariam Y, Adejoh, Zakariah A. Expandable tubular technologies ‘Technology gaps and the way forward’. Global Journal of Researches in En- gineering Chemical Engineering 2011;11(7):1e8. [10] Annual US Geothermal Power Production and Development Report April 2012; Geothermal Energy Association, p. 372. [11] Sanyal SK. Levelizee cost of geothermal power e how sensitive is it? GRC Transactions 2005;29:459e65. [12] DiPippo R. Geothermal power plants: principles, applications and case studies. Oxford, England: Elsevier Advanced Technology; 2005. [13] DiPippo R. Small geothermal power plants: design, performance and eco- nomics. GHC Bulletin 1999:1e8. [14] Lai NA, Wendland M, Fischer J. Working fluids for high-temperature organic Rankine cycles. Energy 2011;36(1):199e211. [15] Saleh B, Koglbauer G, Wendland M, Fischer J. Working fluids for low- temperature organic Rankine cycles. Energy 2007;32(7):1210e21. [16] Brasz Lars J, Bilbow William M. Ranking of working fluids for organic Rankine cycle applications. In: International Refrigeration and Air Conditioning Con- ference, Purdue 2004. p. 722e9. [17] Schuster A, Karellas S, Kakaras E, Spliethoff H. Energetic and economic investigation of Organic Rankine Cycle applications. Applied Thermal Engi- neering 2009;29(8e9):1809e17. [18] Heberle F, Preißinger M, Brüggemann D. Zeotropic mixtures as working fluids in organic Rankine cycles for low-enthalpy geothermal resources. Renewable Energy 2012;37(1):364e70. [19] Angelino G, Colonna di Paliano P. Multicomponent working fluids for organic Rankine Cycles (ORCs). Energy 1998;23(6):449e63. [20] Chen H, Goswami DY, Stefanakos EK. A review of thermodynamic cycles and working fluids for the conversion of low-grade heat. Renewable and Sus- tainable Energy Reviews 2010;14(9):3059e67. [21] Liu B-T, Chien K-H, Wang C-C. Effect of working fluids on organic Rankine cycle for waste heat recovery. Energy 2004;29(8):1207e17. [22] Sotirios K, Andreas S. Supercritical fluid parameters in organic Rankine cycle applications. International Journal of Thermodynamics 2010;11(3): 101e8. [23] Chen H, Goswami DY, Rahman MM, Stefanakos EK. A supercritical Rankine cycle using zeotropic mixture working fluids for the conversion of low-grade heat into power. Energy 2011;36(1):549e55. [24] Mikielewicz D, Mikielewicz J. A thermodynamic criterion for selection of working fluid for subcritical and supercritical domestic micro CHP. Applied Thermal Engineering 2010;30(16):2357e62. [25] Madhawa Hettiarachchi HD, Golubovic M, Worek WM, Ikegami Y. Optimum design criteria for an Organic Rankine cycle using low-temperature geothermal heat sources. Energy 2007;32(9):1698e706. [26] Guo T, Wang HX, Zhang SJ. Fluids and parameters optimization for a novel cogeneration system driven by low-temperature geothermal sources. Energy 2011;36(5):2639e49. [27] Guo T, Wang HX, Zhang SJ. Selection of working fluids for a novel low- temperature geothermally-powered ORC based cogeneration system. Energy Conversion and Management 2011;52(6):2384e91. [28] Siddiqi MA, Atakan B. Alkanes as fluids in Rankine cycles in comparison to water, benzene and toluene. Energy 2012;45(1):256e63. [29] Schuster A, Karellas S, Aumann R. Efficiency optimization potential in su- percritical Organic Rankine Cycles. Energy 2010;35(2):1033e9. [30] US Greenhouse Gas Inventory Report. Washington DC: US Environmental Protection Agency. http://epa.gov/climatechange/emissions/usinventoryreport. html; April 2012. [31] Kramer D. Scientists poke holes in carbon dioxide sequestration. Physics Today 2012;65(8):22e4. [32] The future of coal e options for a carbon constrained world. Massachusetts Institute of Technology; 2007. p. 192. [33] Buhre BJP, Elliott LK, Sheng CD, Gupta RP, Wall TF. Oxy-fuel combustion technology for coal-fired power generation. Progress in Energy and Com- bustion Science 2005;31(4):283e307. % Preheating 0 10 20 30 CO2 exit Working fluid reject temperature, C temperature, C 20 118 55 109 65 72 85 23 Author's personal copy A. Ram Mohan et al. / Energy 57 (2013) 505e512 511 power generated from the EGS in all the cases is substantially sufficient to recover the power lost to recompress CO2 for subse- quent recirculation. 7. Conclusions Pairing IGCC with EGS, in addition to producing electricity from the organic Rainkine cycle, recovers the work done to compress the CO2 from IGCC for sequestration. This process facilitates the simultaneous sequestration of CO2 and extraction of geothermal heat and is particularly attractive in arid regions where scarce water need not be expended. Among the four fluids R134A, ammonia, n-Butane and neopentane used for process modeling of ORC, the power generated (49 MWe) and the efficiency (23%) at which it is generated is highest for ammonia. The possible tem- perature at which CO2 was discharged from the binary heat exchanger was highest for R134A and lowest for n-butane. Considering the corrosive nature of working fluid, ozone depletion potential and greenhouse gas potential, n-Butane and neopentane can be considered as the potential candidates for the working fluids in ORC. Addition of the preheater facilitates the extraction of heat from the hot outgoing fluid leaving the turbine so that it rejects its latent heat to the condenser at the lowest possible temperature. The recuperator also gives an opportunity to add a second Rankine cycle so that more power can be generated discharging both the CO2 and the working fluid at the lowest possible temperatures. Acknowledgment This material is based upon work supported by the United States Department of Energy under Award Number DE-EE0002739. The authors would also like to thank Drs. Vis Visvanathan, Yaw Yeboah and Jonathan Mathews for their valuable suggestions. Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof. References [1] Mock JE, Tester JW, Wright PM. Geothermal energy from the earth: Its po- tential impact as an environmentally sustainable resource. Annual Review of Energy and the Environment 1997;22:305e56.

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