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ADVANCED MICROTURBINE SYSTEMS Final Report for Tasks 1 Through 4 and Task 6

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ADVANCED MICROTURBINE SYSTEMS Final Report for Tasks 1 Through 4 and Task 6 ( advanced-microturbine-systems-final-report-tasks-1-through-4 )

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PROCEEDINGS OF ASME TURBO EXPO 2004 ASME TURBO EXPO 2004: POWER FOR LAND, SEA, AND AIR JUNE, 2004; VIENNA, AUSTRIA GT2004-54092 Development and Evaluation of Environmental Barrier Coatings for Si-based Ceramics Tania Bhatia, Venkat Vedula, Harry Eaton, Ellen Sun, John Holowczak and Gary Linsey United Technologies Research Center East Hartford, CT, USA. ABSTRACT Environmental barrier coatings (EBCs) are being developed for silicon carbide (SiC) based composites and monolithic silicon nitride (Si3N4) to protect against the accelerated oxidation and subsequent silica volatilization in high temperature, high-pressure steam environments encountered in gas turbine engines. While EBCs for silicon carbide (EBCSiC) have been demonstrated in combustor liner applications, efforts are ongoing in the development of EBC systems for silicon nitride (EBCSiN). The challenges of adapting EBCSiC to monolithic Si3N4 are discussed in this paper. Progress in the area of EBCSiN including development and performance during field tests and tests simulating engine conditions are reviewed. INTRODUCTION Silicon-based monolithic ceramics (Silicon Carbide and Silicon Nitride) and ceramic-matrix composites (CMCs) are attractive materials for use in gas turbine engine hot sections due to their high temperature mechanical and physical properties as well as lower density than metals. Potential gas turbine ceramic components include combustor liners, vanes, rotors and shrouds. One of the key material requirements for these components is that they withstand high temperatures and pressures for extremely long duration under steam-rich environments. Steam- stability has been shown to be a problem in SiO2 forming ceramics (SiC and Si3N4) [1-5] due to the accelerated oxidation and recession of silicon carbide and silicon nitride owing to the formation of volatile Si(OH)4 species in high temperature exposure to steam. Environmental Barrier Coatings (EBCs) have been developed for SiC/SiC CMCs and are key to realizing the potential of Si-based materials for high temperature gas turbine applications [6]. EBCs developed for SiC CMCs have been successfully deployed for protection of CMC combustor liners in Solar Centaur 50S engines and have accumulated over 50,000 hours of engine tests at temperatures in the 1150°C- 1200°C (2100-2200F) range [6-9]. Results on the environmental protectiveness of EBCSiC when applied to Si3N4 have been discussed by Sun et. al [10] and More et. al [11]. This paper discusses some important challenges that affect the direct application of the EBCSiC to Si3N4 based both on experimental results and finite element analysis on coated components. 132 Copyright © 2004 by ASME

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