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Figure 8-13: Dependence of CV on pressure for pure CO2.a) Cvlit data (Zhang et al., 2002c) b) data from Molecular Dynamics simulation c) data from NIST database.............................128 Figure 9-1: Pair correlation function for mixture of CH4-CO2 at different densities ....................133 Figure 9-2: Comparison of pair correlation function obtained for pure CO2 (SS) and mixture of CO2-CH4 (Ss) at T = 308.15 K and density equal to 272.79 kg/m3. ....................................133 Figure 9-3: Coordination number of CO2 molecules around a methane molecule` (solid line) and coordination number (dashed line) of a homogeneous fluid at same density. .....................136 Figure 9-4: Coordination number of CO2 molecules around a water molecule` (solid line) and coordination number (dashed line) of a homogeneous fluid at same density ......................138 Figure 9-5: Dependence of tracer diffusion coefficient on pressure of i) a CO2 molecule in pure CO2 ii) a CH4 molecule in CO2 and iii)a H2O molecule in CO2 .Solutions 0.1mol% and temperature 308.15K...........................................................................................................140 Figure 9-6Dependence of Cv on pressure for pure CO2, CH4-CO2 and H2O-CO2 systems (0.1mol% mol) at 308.15K ..................................................................................................141 viiPDF Image | MOLECULAR SIMULATION STUDIES IN THE SUPERCRITICAL REGION
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