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3. fir-blown solid fuel gasification; and 4. Qxygen-blown solid fuel gasification. Selection of Operational Conditions The selection of a design temperature for fluidized bed gasification is influenced by consideration of: 1. The kinetics of the chemical reactions (higher reaction rates and degree of completion generally favored at higher temperatures); 2. The desired H2/CQ ratio (higher ratios generally favored at lower temperatures); 3. The thermal efliciency of the process (generally favored at lower temperatures); and 4. Structural, mechanical and material integrity and cost (generally favored at lower temperatures). AtargetHdCQratioof-2 wasselectedbasedonliquidssynthesisrequirements. A parametric study using the process model indicated that at least according to the equilibrium approximation, this composition will be achieved at a temperature of about 1200-1300F;a reviewoftheempiricalliteraturesupportedthisrange. Therefore,atargetdesigntemperatureof 1300Fwas chosen although it is expected that as much as rt 200F flexibility will be available operationally. The results of this parametric study are shown graphically in Figure 1 and Figure 2. Figure 1: Equilibrium CompositionPredictionfor Nominal Design Feedstock (Air Oxidant) PD.8360793.2 25 8 20 ‘33 c 10 n >” 4. 0> 1 5 Q) 0c 05 0 0 500 1000 1500 2000 Temperature (F) 9PDF Image | THE APPLICATION OF KENTUCKY POWER
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