Thermodynamic investigation of waste heat recovery

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Thermodynamic investigation of waste heat recovery ( thermodynamic-investigation-waste-heat-recovery )

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25 20 15 10 5 0 cyclopentane-hexane cyclopentane-pentane hexane-pentane butane-cyclopentane butane pentane butane-hexane R245fa butane-propane cyclopentane-propane pentane-propane 0 10 20 30 40 50 60 Maximum operation pressure (bar) Fig. 4. Energetic efficiency of the binary zeotropic mixtures at 50/50 concentration In Fig. 4 the thermal efficiency of the binary mixtures of Table 4 is plotted against the maximum operation pressure of the ORC. Similarly to the case of pure fluids, there is a positive correlation between the thermal efficiency of the working fluid, the operation pressure and its critical temperature. Cyclopentane/Hexane and Cyclopentane/Pentane (with critical temperatures 236.50 oC and 217.55 oC respectively) have the highest thermal efficiencies while Pentane/Propane (Tcrit=146.62 oC), Hexane/Propane (Tcrit=165.57 oC) and Butane/Propane (Tcrit=124.33 oC) have the lowest thermal efficiencies. 3. Results and discussion The results of the simulations are organized in the following manner: for each heat source temperature, the exergy efficiency is plotted as a function of the operation pressure for a) pure fluids, b) binary fluid mixtures for subcritical and supercritical conditions. The pure fluids and the binary mixtures exhibiting the maximum exergy efficiency for subcritical and supercritical operating pressures are identified and their performance evaluation and other technical operation parameters are calculated and discussed. 3.1. Heat source temperature of 150 oC Due to the relatively low heat source temperature, the minimum pinch point requirement in the heater is not met for supercritical pressures for any of the pure fluids/mixtures examined, since their critical temperatures are substantially high. Therefore, the results shown refer only to the subcritical pressure range. The mixture of Hexane/Propane has a very small operating range between 5-7 bar with a low exergy efficiency (2-4%), so it is unnecessary to plot these results along with the other mixtures. 12 Energetic efficiency (%)

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Thermodynamic investigation of waste heat recovery

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