Analysis for Recovering Energy from Industrial Waste Heat

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Analysis for Recovering Energy from Industrial Waste Heat ( analysis-recovering-energy-from-industrial-waste-heat )

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1 SURVEY OF CHEMICAL EMISSIONS Table 42 shows that the amount of methane recovered from landfills increased from 19% in 1990 to 40% in 2004. However, while the gas-to-energy conversion increased during this period, the amount of methane flared also increased significantly. This flared CH4 presents an additional opportunity to capture 160 PJ. The flared CH4 was included in our analysis as potential for energy capture from landfill emissions and, added to 538 PJ, yielded 698 PJ. The energy calculated in Tables 41 and 42 agree with the numbers in the general survey of industrial emissions. These numbers reveal that landfills can provide a significant source of energy. Table 42. Energy Content of Methane Emissions from Landfills (PJ) Activity 1990 1993 1997 2001 MSW Generation 646 697 769 833 Large Landfills 252 274 315 359 Medium Landfills 322 347 373 391 Small Landfills 71 76 80 83 Industrial Generation 45 49 54 58 Potential Emissions 691 745 822 891 Emissions avoided 66 107 211 293 Landfill Gas-to-energy 41 50 81 133 Flare 26 57 130 160 Oxidation at MSW Landfills 58 59 56 54 Oxidation at Industrial Landfills 5 5 5 6 Net emissions 562 575 550 538 % recovery 19 23 33 40 Cement Industry The cement industry predominantly emits CO2, but CH4 and N2O may also be released through combustion. The total emission depends on whether Portland cement or Masonry cement is produced. Portland cement is made with the addition of gypsum, which has no additional emissions. Masonry cement requires the addition of lime. In the U.S. inventory, emissions associated with lime manufacture are not included as cement production, but are included in lime manufacturing. Process-related emissions are defined as emissions created during chemical reaction converting limestone to CaO and CO2. Combustion-related emissions result from combustion of fuel for heat and for generation of electricity. The emissions corresponding to the dry and wet processes are 224.2 and 249 kg C/short ton [14]. The U.S. GHG Inventory does not include combustion-related emissions separately as part of the emissions inventory. The annual cement production in the United States is 90 MMtons, or 90 Gg. The combustion-related CO2 emission is 35.3 Tg, which corresponds to 3.7% of combustion-related emission in the industrial sector, while process-related CO2 emission is 41.4 Tg CO2. 39

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