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Supercritical Carbon Dioxide Circulated EGS Combined with IGCC in New Mexico demonstrate is the advantages of higher oxygen concentrations and likewise higher operating temperatures. Although the equilibrium values favor lower oxygen inputs, the benefits in operation seen from elevated temperatures in the areas of kinetics and mass transfer offset the losses in cold gas efficiency. These factors aside, this calculation proves the merit of partial oxidation in relation to carbon monoxide formation. Figure 37 shows the effects of equivalence ratios on the hydrogen gas and steam concentrations. The increase in hydrogen gas is best explained by an increased use of water in coal oxidation. As the oxygen supply continues to decrease, the water molecules present in the coal water slurry oxidizes a higher percentage of the fuel source. 0.6 0.5 0.4 0.3 0.2 0.1 0 12345 Equivalence Ratio H2 H2O Figure 37: Equivalence Ratio vs. Equilibrium Mole Fraction When water comes in contact with the coal, this oxidation process emits hydrogen gas as one of its products. Overall, Figure 36 and Figure 37 adequately show the effects of partial oxidation and steam reformation on an equilibrium synthesis gas composition. Still, this case does not account for the changes in the time required to achieve equilibrium. In practice, the advantages of increased product gases are often rejected in favor of faster reaction rates at the lower equivalence ratios. The second parametric analysis was designed to demonstrate the composition effects seen at thermodynamic equilibrium when the water concentration is varied in the coal water slurry. As the initial mole fraction of water was varied the following trends were observed. Penn State University | 4.3 Gasifier 63 Equilibrium Mole FractionPDF Image | GREAT NECK WATER POLLUTION CONTROL DISTRICT NASSAU COUNTY, NEW YORK MICROTURBINE INSTALLATION FEASIBILITY STUDY
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