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Supercritical Carbon Dioxide Circulated EGS Combined with IGCC in New Mexico Figure 46: Effects of variable dilution methods and inlet temperatures on flame temperature (Chiesa & Lozza, 2005) As the combined cycle operations in this plant are part of a larger system, outside data from contributing group members was applied. It was determined that the flow of hydrogen available to the gas turbine from the gas-water shift reactor was 4.42kmol/sec. This stream was assumed to be 100 percent pure hydrogen. For the calculations of reaction heats, it was assumed that only 3 reactions occurred in the combustion process: hydrogen and oxygen to water, nitrogen and oxygen to nitrogen dioxide, and nitrogen and water to nitrogen monoxide. Gas phase thermochemistry data was obtained from The National Institute of Standards and Technology reference database number 69, in the form of temperature variant coefficients for equation 4.10. Data for variables A-F are shown in appendix table 4.5, and T is the temperature of an environment (National Institute of Standards and Technology, 2008). 4.10 The heats of formation were then used to calculate, in accordance with the thermodynamic principle displayed in equation 4.11, total heats for each of the 3 reaction mechanisms considered, displayed in equations 4.12-4.14. Where H is hydrogen, O is oxygen, and N is nitrogen; while ∆H° is the change in enthalpy of the reactions based on moles of each reactant and product present.c Penn State University | 4.5 Power Generation 75PDF Image | GREAT NECK WATER POLLUTION CONTROL DISTRICT NASSAU COUNTY, NEW YORK MICROTURBINE INSTALLATION FEASIBILITY STUDY
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