EPSRC Thermal Management of Industrial Processes

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EPSRC Thermal Management of Industrial Processes ( epsrc-thermal-management-industrial-processes )

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• the cost of the storage unit (storage medium, the containers and insulation, and the operating cost). This section examines the types of TES technologies available and whether the applications are for high-grade or low-grade heat. TES can be in the form of stored cold as well as heat. The types of TES methods being investigated discussed in detail in this report are: a) Phase Change Material (PCM)/ latent heat storage; b) Thermoelectric materials; c) Magnetic refrigeration; d) Chemical sorbent/ bond storage; and e) Sensible heat 4.1 Phase change materials for latent heat storage 4.1.1 Description Latent heat thermal energy storage is attractive as it provides a high-energy storage density. The high-energy storage density is due to phase change either by freezing/melting or boiling/condensing, and this material is described as a phase change material (PCM). The study of PCMs was pioneered by Telkes and Raymond (1949). PCM was only extensively researched during the energy crisis of late 1970s and early 1980s for use in different applications especially for solar heating systems (Telkes, 1980; Pillai and Brinkworth, 1976; Feldman et al, 1984; Bell and Smith, 1980; Kimura and Kai, 1984; Solomon, 1979; Garg and Nasim, 1981; Knowles, 1983; Miller, 1983). The intensity of the research tailed off after the energy crisis until recently. Relative to sensible heat energy storage systems, PCM requires a smaller weight and volume of material for a given amount of energy, and has the capacity to store heat of fusion at a constant or near constant temperature. Morrison and Abdel-Khalik (1978) and Ghoneim (1989) demonstrated that to store the same amount of energy in paraffin for a given mass: • a rock (sensible heat storage material) requires more than seven times, and; • Na2SO4.10H2O requires more eight times the storage mass of paraffin. The criteria that govern the selection of PCM are (Abhat, 1983; Regin et al, 2008): • Possess a melting point in the desired operating temperature range; • Possess high latent heat of fusion per unit mass; • High specific heat to provide additional significant sensible heat storage; • High thermal conductivity, for ease of for charging and discharging; • Small volumetric changes during phase transition, hence a simple container and heat exchanger geometry can be used; • Exhibit little or no sub-cooling during freezing; 22

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