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Table 13: Techniques for enhancing heat transfer in reactor bed for chemical heat pumps (Fujioka et al, 2008). Heat transfer Preparation technique promoter Reaction couple Expanded graphite Simple mixing Impregnation of aqueous solution of salt using EG, dehydration and calcination Impregnation of aqueous solution of salt into compressed EG, dehydration and calcination Mixing activated carbon with compressed EG using resin as a binder CaCl2/NH3 (Valkov et al, 2002) CaCl2/CH3OH (Hirata et al, 2003) CaCl2/CH3NH2 (Fujioka et al, 2003) CaCl2/CH3NH2 (Mauran et al, 2003) MnCl2/NH3 (Han and Lee, 1999; Mauran et al, 2003) CaCl2/NH3 (Han and Lee, 199) BaCl2/NH3 (Han and Lee, 199) Activated Carbon/CO2 (Goetz, and Guillot, 2001) Carbon fibre Impregnation of aqueous solution of salt into fibre and dehydration Insertion of carbon fibre brush into bed Formation of an intercalation compound CoCl2/NH3 (Aidom and Ternan, 2002) MgO/H2O (Nakaso et al, 2004) MnCl2/HN3 (Dellero et al, 1999) Metal foam (Cu, Ni) Impregnation of a suspension salt, compression and calcination Zeolite/H2O Activated carbon/CH3OH (Guilleminot et al, 1993) Resin Coating particles with resin network (polyanilin) Zeolite/H2O (Hu et al, 1997) Aluminium hydroxide Mixing, compression and calcination Insertion of fins into bed Zeolite/H2O (Pino et al, 1996) CaO/H2O (Ogura et al, 1991) Metal fin or tube Integration of reactant with heat exchanger by coating fin tubes with an adsorbent layer Forming monolithic carbon discs and insertion into aluminium fins Silica gel/H2O (Fujisawa et al, 2002), Zeolite/ H2O (Freni et al, 2004) Activated carbon/NH3 (Tamainot-Telto and Critoph, 1997) 48PDF Image | EPSRC Thermal Management of Industrial Processes
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