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Low-Grade Heat Conversion into Power Using Small Scale Organic Rankine Cycles

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Low-Grade Heat Conversion into Power Using Small Scale Organic Rankine Cycles ( low-grade-heat-conversion-into-power-using-small-scale-organ )

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desirable. Chemical decomposition of the fluid not only reduces the plant efficiency and makes the replacement of the fluid necessary but can produce non-condensable gases which have corrosive effects on the materials of the system. In order to study the fluids decomposition, two methods are available: the dynamic loop tests and the static capsule tests. In Table 4.4 are displayed the maximum stability temperature of some fluids. Fluid R227ea R23 R236fa R143a R245fa R134a R141b R13I1 R7146 R125 MST (oC) 425 400 400 350 300 368 90 102 204 396 Material Stainless steel (AISI 316) Stainless steel (AISI 316) Stainless steel (AISI 316) Stainless steel (AISI 316) Stainless steel (AISI 316) Stainless steel Stainless steel Stainless steel Stainless steel Stainless steel # References Angelino and Invernizzi (2003) # # # # Calderazzi and Colonna di Paliano (1997) # # # # Stine and Geyer (2001) Table 4.4: Maximum stability temperature (MST) of some fluids Methanol 175-230 Toluene 400-425 R113 175-230  Safety properties ## ## The ASHRAE 34 safety classification that applies for refrigerants can be used. This classification is based on two key parameters: the toxicity and the flammability. Toxicity can be identified by some numbers such as TLV (Threshold Limit Value). Flammability is generally identified by the LFL (Lower flammability limit) and the HOC (Heat of Combustion). The ASHRAE standard 34 is made of two classes of toxicity (A: refrigerants for which toxicity has not been identified at concentrations less than or equal to 400 ppm and B: refrigerants for which there is evidence of toxicity at concentrations below 400 ppm) and three groups of flammability characteristics (1: refrigerants that do not show flame propagation when tested in air at 21 oC and 101 kPa, 2: refrigerants having a LFL> 0.10 kg/m3 at 21 oC and 101 kPa and a HOC< 19 kJ/kg and 3: refrigerants that are highly flammable as defined by a LFL≤ 0.10 kg/m3 at 21 oC and 101 kPa or a HOC≥ 19 kJ/kg). The matrix shown in Table 4.5 was adopted for an easy identification of the safety level of any substance. From this classification, the most desirable class is A1. In addition to the aforementioned desirable safety properties, the working fluid should be non-explosive and non-radio-active. Table 4.5 - ASHRAE 34 Refrigerant Safety Classification Higher flammability Lower flammability No flame propagation Lower toxicity A3 A2 A1 Higher toxicity B3 B2 B1 Page | 89

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