Modeling of a Low Temperature Rankine Cycle for Small Scale Cogen

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Modeling of a Low Temperature Rankine Cycle for Small Scale Cogen ( modeling-low-temperature-rankine-cycle-small-scale-cogen )

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Sylvain Quoilin Chapter 2 : Low temperature heat recovery A quick review of the literature about low temperature Rankine cycles gives an idea of the usual working fluids used in ORC systems. Table 1 and 2 give the main characteristics of those fluids, from an environmental and thermodynamic point of view. Refrigerant R­11 R­22 R­113 R­123 R­134a R­245fa R­717 (ammonia) R­601 (n­pentane) R­601a (isopentane) Atmospheric ASHRAE Level lifetime of safety 45 A1 12.0 A1 85 A1 1.3 B1 14.0 A1 7.6 B1 B2 ODP Net GWP 100 year (2102) 1 3660 0.034 1710 0.90 5330 0.012 53 ~0 1320 ~0 1020 ~0 <1 ~0 ~20 ~0 ~20 Phase out Year 1996 2020 1996 2030 Table 1: Environmental data for historical, current, and candidate chiller refrigerants A first selection can be achieved among those fluids given the working temperature range. The application envisaged in the present work have a heat source temperature ranging from 100 to 200 °C and an heat sink temperature ranging from 10 to 50 °C. It is obvious that R­22 and R­134a can be eliminated, their temperature range being too low (see table 2). In the same manner, water, benzene, toluene and p­xylene have a too high temperature range and can be eliminated as well. From an environmental point of view, R­11 and R­113 have a very high ozone depleting potential (ODP), and were phased out in 1996 by the Montreal protocol. Therefore, they won't be taken into account in this work. 16

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