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polarity. A large specific surface area is preferable for providing large adsorption capacity, but the creation of a large internal surface area in a limited volume inevitably gives rise to large numbers of small sized pores between adsorption surfaces. The size of the micropores determines the accessibility of adsorbate molecules to the internal adsorption surface, so the pore size distribution of micropores is another important property for characterizing adsorptivity of adsorbents. Especially materials such as zeolite and carbon molecular sieves can be specifically engineered with precise pore size distributions and hence tuned for a particular separation. Figure 1- Mechanism of adsorption and desorption Surface polarity corresponds to affinity with polar substances such as water or alcohols. Polar adsorbents are thus called "hydrophillic" and aluminosilicates such as zeolites, porous alumina, silica gel or silica-alumina are examples of adsorbents of this type. On the other hand, nopolar adsorbents are generally "hydrophobic". Carbonaceous adsorbents, polymer adsorbents and silicalite are typical nonpolar adsorbents. These adsorbents have more affinity with oil or hydrocarbons than water. 4PDF Image | Thermochemical Heat Pump
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