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• Phase-change If the material changes its phase at a certain temperature while heating the substance then heat is stored in the phase change. Reversing, heat is dissipated when at the phase change temperature it is cooled back. The storage capacity of the phase change materials is equal to the phase change enthalpy at the phase change temperature + sensible heat stored over the whole temperature range of the storage. • Chemical reactions The sorption or thermo chemical reactions provide thermal storage capacity. The basic principle is: AB + heat A+B; using heat a compound AB is broken into components A and B which can be stored separately; bringing A and B together AB is formed and heat is released. The storage capacity is the heat of reaction or free energy of the reaction. Figure 17- Principals of thermal energy storage Materials are the key issues for thermal storage. There are a large range of different materials that can be used for thermal storage as shown by Table 1. 19PDF Image | Thermochemical Heat Pump
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