CONVERTING NATURAL GAS AND CARBON DIOXIDE TO METHANOL

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CONVERTING NATURAL GAS AND CARBON DIOXIDE TO METHANOL ( converting-natural-gas-and-carbon-dioxide-to-methanol )

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TABLE 2 COMPARATIVE ANALYSIS FOR METHANOL PRODUCTION I. I. CONV. 1. CONV. SIEAM CONV. STEAMAND Iv.Presentluv. PROCESS REF. Co2REF. 602mm co2Gasif. v.PresentInv. H,Recycle Energy for process (Kcal/mol MeOI-l') YSClC-lMeOl-l MeOH/Cl-L (mollrml) C02 Emission (molC02Imol MeOH) Gasi?er Shift or Reformer Reactor Acidgas removal Carbon yield M01 ClMol MeOH No.of 2 4 2 3 2 2 Reactors 60 45 45 39 27 31 0.95 1.04 1.01 0.85 0.62 0.58 1.05 0.96 0.99 0.68 0.13 0.00 YES YES NO YES N0 N0 NO YES NO NO NO NO 0 0 0 0.5 1.5 1.73 Percent (:02 BASE -9 —6 reduction from base % What isclaimed: 35 as 100 Removing the hydrogen gas from the top of the bath;and iv. collecting the elemental carbon 01f the top of the liquid Surface of the ham; and l.A processfortheproductionofmethanolfrommethane containing natin'al gas comprised of: decomposing step is comprised of: i.Bubbling the methane through a bath comprised of a molten material operating at a temperature of at least 800° C. and a pressure of l to 10 am; crackingsaidmethanethroughtheuseofsaidmolten 40 moltenmetaliron. material such that elemental carbon and hydrogen gas areformed; * * * * * 5,767,165 30 a. Thermally decomposing said methane to produce hydrogengasandelementalcarbon;whereinthis35 b.Reactingsaidhydrogengaswithcarbondioxideina IV.PresentInv. methanol synthesis reactor in the presence of a catalyst to form a product containing methanol. 2. The process of claim 1 wherein the molten material is selected from the group comprising molten metal tin and

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