HYBRID SUPERCRITICAL POWER CYCLE

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HYBRID SUPERCRITICAL POWER CYCLE ( hybrid-supercritical-power-cycle )

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US 2012/0186219A1 Jul.26,2012 HYBRIDSUPERCRITICALPOWERCYCLE WITHDECOUPLEDHIGH-SIDEAND LOW-SIDE PRESSURES FIELD OF THE INVENTION [0001] Thepresentinventiongenerallyrelatestopower generation With a secondary source of carbon dioxide from either process byproducts or combustion exhaust. In all embodiments, the present invention utiliZes at least one poWergeneratingcycleproducingCO2 containingemissions andWithatleastonepoWergeneratingcycleusingsupercriti cal carbon dioxide “ScCO2” as a Working ?uid. BACKGROUND OF THE INVENTION [0002] Energyef?ciencyhasimportantimpactonbotheco nomics of operating costs and carbon dioxide “CO2” emis sions. The production of fuels from biomass often has byproducts consisting of carbon dioxide, and in most cases the carbon dioxide is at an exergy level su?icient to yield poWergeneration.One suchsourceofcarbondioxideisthe catalytic conversion of cellulosic biomass into liquid and/or gaseous fuels.Another source ofcarbon dioxide isthe com bustionexhaustofhightemperatureindustrialprocessesand/ orpoWergenerationcycles(a.k.a.topcycle). [0003] TraditionalpoWergenerationcyclesusingsuper critical carbon dioxide “ScCO2” have distinct challenges associatedWithatleastoneofCO2 leakagefromtheother Wiseclosedloopcycle,andthedirectimpactofCO2 Within the high pressure side of the closed loop cycle on the loW pressure side of the closed loop cycle and vice versa. [0004] Thecombinedlimitationsofeachindividualcom ponentbeingtheoperationofpoWergenerationcyclesusing ScCO2 as a bottom cycle to a top cycle poWer generation cyclethathasbothWasteheatandCO2 emissions. SUMMARY OF THE INVENTION [0005] Thepresentinventionpreferredembodimentrelates to the decoupling of the high pressure side of a Waste heat driven poWer generation cycle from the loW pressure side. The utiliZation of a high pressure side storage system and a loW pressure side storage system combined With an onsite CO2 source resulting directly from either combustion exhaust or secondary process byproduct. The onsite CO2 source enables the high pressure side “high-side” to have its ScCO2 Working ?uid to be sourced from either or both the high-sidestoragetankasabufferedCO2 source(inpartor entirely such as in a compressed air energy storage), or entirely/in part from pressure increasing device (e.g., tur bocompressor, turbopump, compressor, or pump) having its source of the loW pressure side “loW-side” of the ScCO2 poWergeneratingcycle.TheabilitytoventCO2 fromeither orboththehigh-sideandloW-sideatanypointofoperationis physically enabled, but more importantly economically enabledbyutiliZingCO2 fromthesecondaryprocess. BRIEF DESCRIPTION OF THE DRAWINGS [0006] FIG.1isasequential?oWdiagramofoneembodi ment of a secondary process that is a biomass to biofuel converteryieldingCO2 andWasteheatinaccordanceWiththe presentinvention; [0007] FIG.2isasequential?oWdiagramofanother embodimentofasecondaryprocessthatisabiomassto biofuelconverteryieldingCO2 andWasteheatinaccordance Withthepresentinvention; [0008] FIG.3isasequential?oWdiagramofoneembodi ment of a decoupled high-side from loW-side Within a Waste heatpoWergenerationCO2cycle,WithbothCO2andWaste heat coupling betWeen a secondary cycle and the Waste heat poWergenerationCO2 cycle; [0009] FIG.4isasequential?oWdiagramofanother embodiment of a decoupled high-side from loW-side Within a WasteheatpoWergenerationCO2 cycle,WithbothCO2 and WasteheatcouplingbetWeenasecondarycycleandtheWaste heatpoWergenerationCO2 cycle. DETAILED DESCRIPTION OF THE INVENTION [0010] Theterm“inthermalcontinuity”or“thermalcom munication”, as used herein, includes the direct connection betWeen the heat source and the heat sink Whether or not a thermal interface material is used. [0011] Theterm“?uidinlet”or“?uidinletheader”,asused herein, includes the portion of a heat exchanger Where the ?uid ?oWs into the heat exchanger. [0012] Theterm“?uiddischarge”,asusedherein,includes theportionofaheatexchangerWherethe?uidexitstheheat exchanger. [0013] The term “expandable ?uid”, as used herein, includes the al ?uids that have a decreasing density at increasingtemperatureataspeci?cpressureofatleasta0.1% decreaseindensityperdegreeC. [0014] Theterm“Working?uid”isaliquidmediumuti liZed to convey thermal energy from one location to another. Thetermsheattransfer?uid,Working?uid,andexpandable ?uid are used interchangeably. [0015] Theterm“supercritical”isde?nedasastatepoint (i.e., pressure and temperature) in Which a Working ?uid is above its critical point. It is understood Within the context of thisinventionthattheWorking?uidissupercriticalatleaston the high side pressure of a thermodynamic cycle, and not necessarily on the loW side of the thermodynamic cycle. [0016] Theterm“ramjet”isarotarydevicethateliminates theneedforaconventionalbladedcompressor(Whenaramjet compressor)andturbine(Whenaramjetexpander)asusedin traditional gas turbine engines. One embodiment of a ramjet isaninside-outsupersoniccircumferentialrotorhavinginte grated varying-area shaped channels in its radially inWard surface, in Which compression, combustion and expansion occur.The“inside-out”designplacesalrotatingpartsunder compressivecentrifugalloading. [0017] Theterm“topcycle”isapoWerconversioncycleat thehighestexergystate(i.e.,havingthemaximum abilityto produceusefulWork,alsosynonymousWithtoppingcycle. [0018] Theterm“CO2source”isanaircompositionthat contains carbon dioxide ranging from 5 percent on a mass fraction basis to a highly enriched air composition up to 100 percent on a mass fraction basis. [0019] Theterm“fuel”isachemicalreactantthatisexo thermic during an oxidation reaction. [0020] Theterm“CO2capturesystem”isamethodof effectivelyisolatingcarbondioxidefromanaircomposition, such as combustion exhaust, by any method ranging from carbonation chemical reaction, adsorption, or absorption.

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