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Sample \ N CO2loading at 25° C. (mole Concentrationof COZ/mole Sample(mole/L) amine) 2.83 0.361 2.90 0.772 2.87 0.195 2.93 0.403 (loWerpart)0.97 0.116 (upperpart)4.5 0.000 2.87 0.264 Sample Condition amine) 0.609 amine) N/A 0.217 0.269 0.147 0.279 0.058 0.138 0.227 0.226 0.208 N/A 0.271 0.195 % Difference N/A 35.63 38.82 30.00 35.27 15.30 23.55 37.27 32.61 42.45 N/A 71.50 33.28 I 15kPaCO2at80°C. 2.79 0.115 100kPaCO2at80°C. 2.88 0.352 TABLE 3 7 9 17 TABLE 2-c0ntinued SolubilitiesofMBA andthesyntheticaminoalcohols(1)to(9)at conditions close to the absorption and stripping columns. Condition OH 15kPaCO2at25°C. 100 kPa CO2 at25° C. 15 kPa CO2 at40° C. 100 kPa CO2 at40° C. 100 kPa CO2 at40° C. 15kPaCO2at55°C. 100 kPa CO2 at55° C. OH 15kPaCO2at40°C. 2.91 100kPaCO2at40°C. 3.00 15kPaCO2at60°C. 2.92 Comment Does not dissolve inWater Phase separation athigh temperature \/\N 100kPac02at60°c.2.96 0.729 H 8 15kPaCO2at80°C. 2.31 100kPaCO2at80°C. 2.89 15kPaCO2at40°C. 2.91 100kPaCO2at40°C. 2.97 15kPaCO2at60°C. 2.91 0.396 0.565 0.695 0.948 0.323 OH /\N 100kPaCO2at60°C.2.81 0.889 Absorption capacity difference of synthetic amino alcohols compared With MEA. MBA 15kPaCO2at40°C. NH2 100 kPa CO2 at40° C. 0.693 HO/\/ 15kPaCO2at60°C.0.490 100kPaCO2at60°C. 0.621 15kPaCO2at80°C. 0.379 100kPaCO2at80°C. 0.586 —\ N J H | N 1 OH OH 15kPac02at40°c. 0.826 100kPac02at40°c. 0.962 15kPac02at60°c. 0.637 100kPac02at60°c. 0.840 15kPac02at80°c. 0.437 100kPac02at80°c. 0.724 15kPac02at40°c. 0.836 100kPac02at40°c. 0.919 15kPac02at60°c. 0.698 100kPac02at60°c. N/A 15kPac02at80°c. 0.650 100kPac02at80°c. 0.781 US 7,910,078B2 CO2 Absorption loading Capacity at25° C. Difference (mole (mole COZ/mole COZ/mole 0.681 0.849 0.541PDF Image | METHOD OF CAPTURING CARBON DIOXIDE FROM GAS STREAMS
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