PROCESS AND SYSTEM FOR CREATING ENHANCED CAVITATION

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PROCESS AND SYSTEM FOR CREATING ENHANCED CAVITATION ( process-and-system-for-creating-enhanced-cavitation )

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US 8,011,431 B2 9 10 oxide-containing surface. Exemplary examples of such aminesinclude,Withoutlimitation,anyamineofthegeneral formula Rl,R2NH or mixtures or combinations thereof, where R1 and R2 are independently a hydrogen atom or a carbyl group having betWeen about betWeen about 1 and 40 carbon atoms and the required hydrogen atoms to satisfy the valence and Where one or more of the carbon atoms can be replaced by one or more hetero atoms selected from the group consisting of boron, nitrogen, oxygen, phosphorus, sulfur or mixture orcombinations thereofand Where one ormore ofthe hydrogen atoms can be replaced by one or more single valence atoms selected from the group consisting of ?uorine, chlorine, bromine, iodine or mixtures or combinations thereof. Exemplary examples of amines suitable for use in this invention include, Without limitation, aniline and alkyl anilines or mixtures of alkyl anilines, pyridines and alkyl pyridines or mixtures of alkyl pyridines, pyrrole and alkyl pyrroles or mixtures of alkyl pyrroles, piperidine and alkyl piperidinesormixturesofalkylpiperidines,pyrrolidineand alkylpyrrolidinesormixturesofalkylpyrrolidines,indole20 and alkyl indoles or mixture of alkyl indoles, imidaZole and alkylimidaZoleormixturesofalkylimidaZole,quinolineand alkylquinolineormixtureofalkylquinoline,isoquinoline andalkylisoquinolineormixtureofalkylisoquinoline,pyra ZineandalkylpyraZineormixtureofalkylpyraZine,quinoxa 25 line and alkyl quinoxaline or mixture of alkyl quinoxaline, acridineandalkylacridineormixtureofalkylacridine,pyri midineandalkylpyrimidineormixtureofalkylpyrimidine, quinaZoline and alkyl quinaZoline or mixture of alkyl quinaZoline, or mixtures or combinations thereof. Suitablephosphateestersinclude,Withoutlimitation,any phosphate ester that is capable of reacting With a suitable aminetoformacompositionthatformsadeformablecoating onametal-oxidecontainingsurfaceorpartiallyorcompletely coatsparticulatematerials.Exemplaryexamplesofsuch35 phosphateestersinclude,Withoutlimitation,anyphosphate esters of the general formula P(O)(OR3)(OR4)(OR5) or mix ture or combinations thereof, Where R3, R4, and OR5 are independently a hydrogen atom or a carbyl group having betWeenaboutbetWeenabout1and40carbonatomsandthe40 requiredhydrogenatomstosatisfythevalenceandWhereone or more of the carbon atoms can be replaced by one or more hetero atoms selected from the group consisting of boron, nitrogen, oxygen, phosphorus, sulfur or mixture or combina tionsthereofandWhereoneormoreofthehydrogenatoms 45 can be replaced by one or more single valence atoms selected from the group consisting of ?uorine, chlorine, bromine, iodine or mixtures or combinations thereof. Exemplary examples of phosphate esters include, Without limitation, phosphateesterofalkanolshavingthegeneralformulaP(O) 50 (OH)x(OR6)yWherex+y:3andareindependentlyahydrogen atom or a carbyl group having betWeen about betWeen about 1 and 40 carbon atoms and the required hydrogen atoms to satisfythevalence and Where one ormore ofthecarbon atoms canbereplacedbyoneormoreheteroatomsselectedfromthe 55 group consisting of boron, nitrogen, oxygen, phosphorus, sulfur or mixture or combinations thereof and Where one or more of the hydrogen atoms can be replaced by one or more single valence atoms selected from the group consisting of ?uorine,chlorine,bromine,iodineormixturesorcombina 60 tionsthereofsuchasethoxyphosphate,propoxylphosphate or higher alkoxy phosphates or mixtures or combinations thereof. Other exemplary examples of phosphate esters include, Without limitation, phosphate esters of alkanol amineshavingthegeneralformulaN[R7OP(O)(OH)2]365 Where R7 is a carbenyl group having betWeen about betWeen about1and40carbonatomsandtherequiredhydrogenatoms to satisfy the valence and Where one or more of the carbon atoms can be replaced by one or more hetero atoms selected fromthegroupconsistingofboron,nitrogen,oxygen,phos phorus, sulfur or mixture or combinations thereof and Where one ormore ofthehydrogen atoms can be replacedby one or more single valence atoms selected from the group consisting of ?uorine, chlorine, bromine, iodine or mixtures or combi nations thereof group including the tri-phosphate ester of tri-ethanol amine or mixtures or combinations thereof. Other exemplary examples of phosphate esters include, Without limitation, phosphate esters of hydroxylated aromatics such asphosphateestersofalkylatedphenolssuchasNonylphenyl phosphate ester or phenolic phosphate esters. Other exem plary examples of phosphate esters include, Without limita tion,phosphateestersofdiolsandpolyolssuchasphosphate estersofethyleneglycol,propyleneglycol,orhigherglycolic structures. Other exemplary phosphate esters include any phosphate esterthan can react With an amine and coated on to a substrate forms a deformable coating enhancing the aggre gatingpotentialofthesubstrate. Suitable solid materials suitable for being coated With the compositions of this invention include, Without limitation, metal oxides and/or ceramics, natural or synthetic, metals, plasticsand/orotherpolymericsolids,solidmaterialsderived fromplants,oranyothersolidmaterialthatdoesormay?nd use in doWnhole applications or mixtures or combinations thereof. Metal oxides including any solid oxide of a metallic element of the periodic table of elements. Exemplary examples of metal oxides and ceramics include actinium oxides, aluminum oxides, antimony oxides, boron oxides, barium oxides, bismuth oxides, calcium oxides, cerium oxides,cobaltoxides,chromiumoxides,cesiumoxides,cop per oxides, dysprosium oxides, erbium oxides, europium oxides, gallium oxides, germanium oxides, iridium oxides, ironoxides,lanthanumoxides,lithiumoxides,magnesium oxides, manganese oxides, molybdenum oxides, niobium oxides, neodymium oxides, nickel oxides, osmium oxides, palladium oxides, potassium oxides, promethium oxides, praseodymium oxides, platinum oxides, rubidium oxides, rheniumoxides,rhodiumoxides,rutheniumoxides,scan dium oxides, selenium oxides, silicon oxides, samarium oxides, silver oxides, sodium oxides, strontium oxides, tan talum oxides, terbium oxides, tellurium oxides, thorium oxides,tinoxides,titaniumoxides,thalliumoxides,thulium oxides,vanadiumoxides,tungstenoxides,yttriumoxides, ytterbium oxides, Zinc oxides, Zirconium oxides, ceramic structures prepared from one or more of these oxides and mixed metal oxides including tWo or more of the above listed metaloxides.Exemplaryexamplesofplantmaterialsinclude, Withoutlimitation,shellsofseedbearingplantssuchasWal nut shells, pecan shells, peanut shells, shells for other hard shelled seed forming plants, ground Wood or other ?brous cellulosic materials, or mixtures or combinations thereof. SurfaceAcidifyingandModifyingCompositions Suitableacidifyingagentsinclude,Withoutlimitation,sul furicacid,phosphoricacid,hydrochlorideacid,nitricacid, carboxylicacids,chloratedcarboxylicacids,carbylsulfonic acids, Where the carbyl group has betWeen about 1 and 40 carbon atoms and the required hydrogen atoms to satisfy the valenceandWhereoneormoreofthecarbonatomscanbe replaced by one ormore hetero atoms selected from the group consisting of boron, nitrogen, oxygen, phosphorus, sulfur or mixture or combinations thereofand Where one or more ofthe hydrogen atoms can be replaced by one or more single valenceatomsselectedfromthegroupconsistingof?uorine, chlorine, bromine, iodine or mixtures or combinations thereof, or mixture or combinations thereof. 30

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