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RECOVERY OF BUTANOL

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RECOVERY OF BUTANOL ( recovery-butanol )

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Stage 9 10 11 12 13 14 15 Stage C. 98.252025 99.729315 100.12846 100.28719 100.39431 100.49026 100.58687 atm Temperature Pressure Heat Liquid Vapor Liquid Vapor Mixed Liquid Vapor duty floW floW feed feed feed product product MJ/hr kg/hr kg/hr kg/hr kghr kg/hr kg/hr kg/hr Temperature Pressure C. atm Heat Liquid Vapor Liquid Vapor duty floW floW feed feed MJ/hr kg/hr kghr kghr kghr 8 100.30332 1.036269 9 100.76828 1.043319 10 101.13588 1.050368 11 101.43569 1.057418 12 101.69116 1.064467 13 101.91862 1.071517 14 102.12867 1.078566 15 99.508871 1.085616 0 354949.471 44426.8042 0 354326.157 43432.6418 0 353962.728 42809.3273 0 353769.003 42445.8987 0 353681.364 42252.1732 0 353658.26 42164.5345 0 353764.202 42141.4305 Stage 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 feed product kghr kg/hr 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 311516.83 product kg/hr 59637.9415 0 0 0 0 0 0 0 0 0 0 0 0 0 0 79.1 0.99 1 315.821 27214.93 8.90E+06 25 79.1 2 0.99 0 0.117 42 0.99 6.79E+06 64.7 84.1 0.99 0.99 1 1 79.1 0.99 3.76E+07 32 98.4 1.04 1.09 0 0 19 20 1.015121 0 1.018646 0 1.022171 0 1.025695 0 1.02922 0 1.032745 0 48853.4454 49100.032 49173.6467 49206.62 49230.7751 49252.6876 30374.8574 31101.5232 31348.1099 31421.7245 31454.6978 31478.853 315007655 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 17751.922 0 1.036269 17366.1216 17751.9221 TABLE 5 Simulated Solvent Column Traf?c and Liquid Mass Composition Pro?le Outputs for Example 1. 1 91.603505 0.986923 2 95.920715 0.993973 3 96.339035 1.001022 4 97.277269 1.008072 5 98.149382 1.015121 6 98.985077 1.022171 7 99.712494 1.02922 0 355943.634 45892.7389 US 8,563,788B2 TABLE 4-c0ntinued SimulatedBUOH ColumnTrafficandliuuidMassCompositionPro?leOutputsforExample1. 0 32298.369 59637.9415 41149.9372 4.83408955 0 32111.9083 50781.5393 0 536.382563 0 364047.199 50058.6959 329463.617 0 0 0 0 0 0 0 0 0 0 0 0 0 2ndliquid floWkg/hr 32279.511 32093.878 50641.234 52462.946 54196.867 55685.162 56832.076 57648.569 58202.157 58569.955 58815.704 58984.779 59106.969 59303.926 311516.83 0 361701.456 52530.3696 0 359371.797 50184.6253 0 357409.569 47854.9674 92576.5773 311516.83 42247.372 Mixed Liquid Vapor 324.932 1004.081 28000 41597.72 42683.8 3.43E+06 0.201 1329.022 69598.092 353.182 966.72 26807.06 42005.59 0.994 1319.902 68812.653 1338.63 1068.954 131500 112291.57 1561588 139295.86 TABLE 6 Simulated Stream Outputs for Example 2. 0 0 0 0 0 0 0 0 0 0 0 0 1stliquid ?oW kg/hr 18.8581326 18.0300995 313405.965 309238.51 305174.93 301724.406 299111.558 297300.902 296124 295392.773 294953.299 294696.585 294551.291 294460.276 0 11 12 19 20 21 30 33 40 41 Temperature C. Pressure atm Vapor Frac Mole FloW kmol/hr Mass FloW kghr Volume FloW l/hr EnthalpyMMBtu/hr —47.593 —61.151 —286.381 —347.534 —64.982 —233.71 —298.692 —466.49 —361.339 Mass FloW kghr 2-BUOH 29985.11 29985.365 4029.378 25955.73 29985.109 18199.6 11.227 OLEYLOH 0.011 0.011 trace 0.011 0.011 99716.45 99716.441 9.56E+06 2.82E+07

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