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US 2012/0055805 A1 Mar. 8,2012 electrolyticcombustion.Anotherembodimentoftheinven tionincludestheelectrolytecompositionWhereintheaque ous solvent comprises at least 50% of said electrolyte on a Wt/vol. basis. Another embodiment of the invention includes the electrolyte composition Wherein the aqueous solvent comprisesfromabout50% toabout95% ofsaidelectrolyte on a Weight to volume basis. Another embodiment of the invention includes the electrolyte composition Wherein a noble gas is dissolved in the aqueous solvent. Another embodiment of the invention includes the noble gas Argon. Another embodiment of the invention includes the noble gas saturatingthesolvent. [0020] Anotherembodimentoftheinventionincludesthe electrolytecompositionWhereintheinorganicsaltcomprises acationselectedfromthegroupconsistingofsodium,lithium and potassium. Another embodiment of the invention may include the inorganic salt comprising an anion selected from the group consisting of ?uoride, chloride, bromide and iodide. Another embodiment of the invention includes the electrolytecompositionWhereintheinorganicsaltcomprises NaCl. Another embodiment of the invention includes the electrolytecompositionWhereintheinorganicsaltcomprises NaI. [0021] Anotherembodimentoftheinventionincludesthe electrolytecompositionWhereintheorganicacidispresentin theelectrolyteataWt/vol.concentrationoffromabout1% to about 10%. Another embodiment of the invention includes the electrolyte composition Wherein the organic acid com prisesapluralityofcarboxylgroups. [0022] Anotherembodimentoftheinventionincludesthe electrolytecompositionWhereintheorganicacidissubstan tially soluble in the electrolyte solution. “Substantially soluble”meanstheorganicacidisatleast10Wt.% solublein theelectrolytesolution.Anotherembodimentoftheinvention includestheelectrolytecompositionWhereinsaidatleastone organicacidsolubilityisfromabout10Weight% toabout90 Weight% soluble. [0023] Anotherembodimentoftheinventionincludesthe electrolytecompositionWhereintheorganicacidcomprisesa main carbon chain having from one to eight carbons in the mainchain(“Cl-C8”). [0024] Anotherembodimentoftheinventionincludesthe electrolytecompositionWhereintheorganicacidisselected from the group consisting ofAcetic acid, Citric acid, Formic acid, Malic acid, Malonic acid, Mandelic acid, Maleic acid, Iso-citric acid, Fumaric acid, Lactic acid, Glycolic acid, Glycericacid,Hexanoicacid,Heptanoicacid,Octanoicacid, Pentanoic acid, Nonanoic acid, Propanoic acid, 3-Hydrox ypropanoic acid, Tartaric acid and 2-Hydroxypropanedioic acid. [0025] Anotherembodimentoftheinventionincludesthe electrolytecompositionWhereintheatleastoneorganicacid iscitricacid.Thecitricacidmaybepresentintheelectrolyte ataconcentrationoffromabout0.05M toabout5.0M. Ina preferredembodiment,theelectrolytecompositionhasacit ric acid concentration of about 0.1 M. Yet another embodi ment of the invention includes the electrolyte composition Wherein the concentration of citric acid is about 0.1M, NaCl is about 0.5 to 5 Weight %, and NaI is present in a trace amount. [0026] Anotherembodimentoftheinventionincludesthe electrolytecompositionWhereintheelectrolyteissaturated With an amount of Argon su?icient to promote cavitation assistedelectrolyticcombustion. [0027] Anotherembodimentoftheinventionincludesthe electrolytecompositionWhereintheorganicacidcomprises the structural formula: WhereinR canbeindividuallyanyofH oranyalkalineearth metal;and [0028] nisfrom2to8. [0029] Anotherembodimentoftheinventionincludesthe electrolytecompositionWhereintheorganicacidcomprises the structural formula: WhereinR canbeindividuallyanyofH oranyalkalineearth metal;and [0030] nisfrom2to8. [0031] Anotherembodimentoftheinventionincludesthe electrolytecompositionWhereintheorganicacidcomprises the structural formula: WhereinR canindividuallybeanyofH oranyalkalineearth metal; [0032] R2canbeeitherOHorCOOR;and [0033] nmaybefrom1to3. [0034] Anotherembodimentoftheinventionincludesthe electrolytecompositionWhereintheorganicacidisanalpha hydroxy acid or a beta-hydroxy acid substantially soluble in Water. [0035] Anotherembodimentoftheinventionincludesan electrolytecompositionofmattercomprisinganaqueoussol vent, at least one inorganic salt dissolved in said solvent, and at least one organic acid or salt thereof, said acid having the folloWingstructuralformula WhereinR canindividuallybeanyofH oranyalkalineearth metal;and [0036] nisfrom2to8. [0037] Theforegoingandotherfeaturesandadvantagesof the present invention Will be apparent from the folloWing more particular description of the preferred embodiments of the invention, as illustrated in the accompanying draWings. BRIEF DESCRIPTION OF THE DRAWINGS [0038] FIG.1isadiagramofa?rstembodimentofa hydrogenproductionsystemaccordingtothepresentinven tion. [0039] FIG.2isadiagramofasecondembodimentofa hydrogenproductionsystemaccordingtothepresentinven tion. [0040] FIG.3isadiagramofaconicalfunnelmemberof FIG. 2. [0041] FIG.4isadiagramofathirdembodimentofa hydrogenproductionsystemaccordingtothepresentinven tion. [0042] FIG.5isadiagramofa?rstcavitationsubsystem accordingtothepresentinvention. [0043] FIG.6isadiagramofasecondcavitationsubsystem accordingtothepresentinvention. [0044] FIG.7isadiagramofthemajorfactorsaffecting hydrogenproduction. [0045] FIG.8isacomerperspectiveofacomputer-aided draWingofasingle-cellsonoelectrochemicalapparatusofthe fourthembodiment.PDF Image | SONOCHEMICAL HYDROGEN PRODUCTION SYSTEM
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