Bringing Redox Flow Batteries to the Grid

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Bringing Redox Flow Batteries to the Grid ( bringing-redox-flow-batteries-grid )

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4.2 Economic strategies to mitigate price volatility and reduce the upfront cost burden of vanadium.......................................................................................................................... 81 5. Conclusions...................................................................................................................... 83 V. Hydrogen evolution mitigation in iron-chromium redox flow batteries via electrochemical purification of the electrolyte ..........................................................................86 1. Introduction..................................................................................................................... 86 2. Methods............................................................................................................................ 92 3. Results and Discussion.................................................................................................... 94 4. Conclusions .................................................................................................................... 105 VI. Conclusions & future work...........................................................................................107 VII. Appendix A – Supporting information for Chapter V ...............................................111 1. Correlation plot of relevant variables for Fe-Cr RFB cell operation ...................... 111 2. Post-mortem spectroscopy of electrodes..................................................................... 113 VIII. Appendix B – Example of techno-economic- and chemistry- informed design of membranes for RFBs, enabled by incorporation of physics-based models..........................114 References ...................................................................................................................................120 Permissions .................................................................................................................................139 8

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